Journal ArticleDOI
Role of silver compounds in promoting the thermal decomposition of ammonium perchlorate
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Galwey et al. as mentioned in this paper investigated the role of silver in promoting the thermal decomposition of ammonium perchlorate (AP) and found that silver metal and silver chloride reduce the induction period to the low temperature reaction of AP and somewhat increase the rate of the subsequent reaction.About:
This article is published in Reactivity of Solids.The article was published on 1986-05-01. It has received 9 citations till now. The article focuses on the topics: Silver oxide & Silver nitrate.read more
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Journal ArticleDOI
Nanocrystalline Transition Metal Oxides as Catalysts in the Thermal Decomposition of Ammonium Perchlorate
TL;DR: In this article, Nanocrystalline transition metal oxides (NTMOs) have been successfully prepared by three different methods: novel quick precipitation method, surfactant mediated method and reduction of metal complexes with hydrazine as reducing agent (Mn2O3).
Journal ArticleDOI
Differential Scanning Calorimetric Study of HTPB based Composite Propellants in Presence of Nano Ferric Oxide
TL;DR: In this article, a comparative study of the thermal decomposition of ammonium perchlorate (AP)/hydroxy terminated polybutadiene (HTPB) based composite propellants has been carried out in presence and absence of nano iron oxide at different heating rates in a dynamic nitrogen atmosphere using differential scanning calorimetry.
Journal ArticleDOI
The non-isothermal decomposition of cobalt acetate tetrahydrate : a kinetic and thermodynamic study
TL;DR: In this paper, the non-isothermal decomposition of cobalt acetate tetrahydrate was studied up to 500°C by means of TG, DTG, DTA and DSC techniques in different atmospheres of N2, H2 and in air.
Journal ArticleDOI
Thermal reactions of selected solids including reactants that melt during chemical change
TL;DR: In this paper, a review of kinetic and mechanistic studies of thermal reactions of initially solid substances are reviewed with emphasis on the evidence that some of these chemical changes proceed with the essential participation of melting.
Journal ArticleDOI
Non-isothermal kinetic and thermodynamic study of the decomposition of lead acetate trihydrate
TL;DR: In this paper, the non-isothermal decomposition of lead acetate trihydrate was studied up to 450°C by means of TG, DTG, DTA and DSC measurements in a dynamic atmosphere of N2 (or dry air).
References
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Journal ArticleDOI
Decomposition and combustion of ammonium perchlorate
Journal ArticleDOI
Thermal decomposition of ammonium perchlorate
TL;DR: In this article, a unified mechanism for sublimation and decomposition of ammonium perchlorate was proposed, which involves proton transfer from NH+4 to ClO-4 ions as the basic step.
Journal ArticleDOI
Decomposition reactions of solids (an experiment in reviewing)
N. J. Carr,Andrew K. Galwey +1 more
Journal ArticleDOI
A melt mechanism for the thermal decomposition of ammonium dichromate
TL;DR: In this article, it was shown that an initial dissociation of the reactant (NH4)2Cr2O7⇌ 2NH3+H2O + 2CrO3 is followed by a sequence of steps by which NH3 and/or NH+4 is oxidized in the CrO3 melt to N2 and N2O, possibly involving the intervention of NH4NO2 and NH4 NO3 respectively.
Journal ArticleDOI
The mechanism of the low-temperature decomposition of NH4ClO4
TL;DR: In this article, the authors investigated the topokinetical aspects of the low-temperature decomposition (LTD) of ammonium perchlorate (AP) crystals, i.e., the nucleation rate (V n ), the rate of nuclei growth (V g ), and their dependence on the concentration of some additives and the temperature.
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