Journal ArticleDOI
Selective Reduction of the CarbonBromine Bond in Bromo Epoxides
TLDR
The controlledpotential electrolysis of various substituted bromo epoxides in acetonitrile at a mercury pool electrode led to selective reduction of the carbon-bromine bond affording the respective epoxide products in 80-90% yield.About:
This article is published in Tetrahedron Letters.The article was published on 1992-03-10. It has received 6 citations till now. The article focuses on the topics: Selective reduction & Epoxide.read more
Citations
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Journal ArticleDOI
Palladium-catalyzed hydrodehalogenations by fluoride activated polymethylhydrosiloxane
TL;DR: Evidence is suggested that the reduction of bromostyrene proceeds differently than previously described, and the hydrodehalogenations described herein are amine free and can be carried out in THF with relatively low loads of catalyst.
Journal ArticleDOI
Use of Electrochemical Methods as an Alternative to Tin Reagents for the Reduction of Vinyl Halides in Inositol Synthons.
Tomas Hudlicky,Christopher D. Claeboe,Larry E. Brammer,Lukasz Koroniak,Gabor Butora,Ion Ghiviriga +5 more
TL;DR: Electrochemical methods provide for selective reduction of vinyl iodides over vinyl bromides, with better yields than analogous tin methodology.
Journal ArticleDOI
Regioselective ring-opening of epoxides by carbazole: a direct preparation of novel N-(β-hydroxyalkyl)carbazoles
TL;DR: In this paper, the influence of various parameters including solvent, base and temperature on the reaction between carbazole and epoxides was studied, which led to the development of a regioselective ring-opening mechanism.
Formation of Alkanes and Arenes by Reduction
Richard C. Larock,Xiaoxia Zhang +1 more
TL;DR: Reduction============Cyclic Alkanes============Arenes============Alkenes======Alkynes======Organic Halides======Amines and Derivatives======Nitro Compounds======Ethers======Alcohols and Phenols======Sulfur Compounds ``(Selenium and Tellurium Compounds")======Aldehydes and Ketones======Acetals======Carboxylic Acids======
Journal ArticleDOI
Proton-transfer reactions in the cathodic reduction of bromohydrins in neutral aprotic media
TL;DR: Polarographic and cyclic voltammetric studies of bromohydrins in acetonitrile showed a single diffusion-limited two-electron irreversible cathodic wave/peak followed by chemical transformations as discussed by the authors.
References
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Journal ArticleDOI
Selective electrochemical reduction of polyfunctional molecules
Journal ArticleDOI
Zur frage der orbitalsymmetriekontrolle cheletroper spaltungen bei vinylencarbonaten
J. Fleischhauer,H.D. Scharf +1 more
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A selective cathodic reduction of β-chlorovinylimines in N,N′ dimethylformamide
TL;DR: The controlledpotential electrolyses of various substituted chlorovinylimines, viz., 4-chloro-3-(N-aryliminomethyl)-2H(1)-benzopyrans in dimethylformamide(DMF) solutions at mercury pool electrode yielded selectively the corresponding chlorine reduced products in moderately good yields.