Journal ArticleDOI
Single-ion triblock copolymer electrolytes based on poly(ethylene oxide) and methacrylic sulfonamide blocks for lithium metal batteries
Luca Porcarelli,Luca Porcarelli,M. Ali Aboudzadeh,Laurent Rubatat,Jijeesh Ravi Nair,Alexander S. Shaplov,Claudio Gerbaldi,David Mecerreyes +7 more
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TLDR
In this article, single-ion conducting polymer electrolytes represent the ideal solution to reduce concentration polarization in lithium metal batteries (LMBs) and are obtained by reversible addition of fragmentation chain transfer polymerization, showing low glass transition temperature (−55 to 7°C) and degree of crystallinity (51-0%).About:
This article is published in Journal of Power Sources.The article was published on 2017-10-01. It has received 121 citations till now. The article focuses on the topics: Lithium & Polymerization.read more
Citations
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Journal ArticleDOI
Benchmarking the performance of all-solid-state lithium batteries
Simon Randau,Dominik A. Weber,Dominik A. Weber,Olaf Kötz,Raimund Koerver,Raimund Koerver,Philipp Braun,André Weber,Ellen Ivers-Tiffée,Torben Adermann,Jörn Kulisch,Wolfgang G. Zeier,Felix H. Richter,Jürgen Janek +13 more
TL;DR: All-solid-state batteries reduced to the bare minimum of compounds, containing only a lithium metal anode, β-Li 3 PS 4 solid electrolyte and Li(Ni 0.6 Co 0.2 Mn 0. 2 )O 2 cathode active material are presented.
Journal ArticleDOI
Innovative Electrolytes Based on Ionic Liquids and Polymers for Next-Generation Solid-State Batteries
TL;DR: Electrolytes based on organic solvents used in current Li-ion batteries are not compatible with the next-generation energy storage technologies including those based on Li metal, so there has been an increase in research activities investigating solid-state electrolytes, ionic liquids, polymers, and combinations of these.
Journal ArticleDOI
Reviewing the current status and development of polymer electrolytes for solid-state lithium batteries
TL;DR: In this paper, the ion transfer mechanism and performance requirements of polymer electrolytes for lithium batteries, the classification and design of polymeric electrolytes, and the essential principles and characterization for electrode/electrolyte interface construction and the research of composite electrolyte.
Journal ArticleDOI
Building Better Batteries in the Solid State: A Review.
TL;DR: Different chemistries are examined, including not only Li-air, Li–O2, and Li–S, but also sodium-ion batteries, which are also subject to intensive research and the challenges toward commercialization are considered.
Journal ArticleDOI
Toward High-Energy-Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytes.
Xiaoen Wang,Robert Kerr,Fangfang Chen,Nicolas Goujon,Nicolas Goujon,Jennifer M. Pringle,David Mecerreyes,Maria Forsyth,Maria Forsyth,Patrick C. Howlett +9 more
TL;DR: Recent advances in the development of novel organic electrolytes are summarized and specific strategies toward developing these electrolytes for Li metal anodes, high-energy-density cathode materials, as well as the optimization of cathode formulations are outlined.
References
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Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
Journal ArticleDOI
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
Zhigang Xue,Dan He,Xiaolin Xie +2 more
TL;DR: In this article, a review of the recent developments and issues concerning polyethylene oxide (PEO) based electrolytes for lithium-ion batteries is presented, including blending, modifying and making PEO derivatives.
Journal ArticleDOI
Electrochemical measurement of transference numbers in polymer electrolytes
TL;DR: In this article, the transference number of lithium and trifluoromethanesulphonate ions in poly(ethylene oxide) at 90°C was measured and a mean value of 0.46 ± 0.02 was reported for lithium.
Journal ArticleDOI
Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries
Renaud Bouchet,Sébastien Maria,Rachid Meziane,Abdelmaula Aboulaich,Livie Liénafa,Jean-Pierre Bonnet,Trang N. T. Phan,Denis Bertin,Didier Gigmes,Didier Devaux,Renaud Denoyel,Michel Armand +11 more
TL;DR: A multifunctional single-ion polymer electrolyte based on polyanionic block copolymers comprising polystyrene segments overcomes most of the above limitations, with a lithium-ion transport number close to unity, excellent mechanical properties and an electrochemical stability window spanning 5 V versus Li(+)/Li.
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Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
Zhigang Xue,Dan He,Xiaolin Xie +2 more