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Journal ArticleDOI

Spectroscopic and crystal-field analysis of new Yb-doped laser materials

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TLDR
In this article, two tools derived from a careful examination of crystal-field interaction are presented to simplify the interpretation of low-temperature spectra of Yb-doped materials.
Abstract
Crystal-field effects are very important as far as laser performances of Yb-doped materials are concerned. In order to simplify the interpretation of low-temperature spectra, two tools derived from a careful examination of crystal-field interaction are presented. Both approaches are successfully applied in the case of new Yb-doped materials, namely Ca3Y2(BO3)4 (CYB), Ca3Gd2(BO3)4 (CaGB), Sr3Y(BO3)3 (SrYBO), Ba3Lu(BO3)3 (BLuB), Y2SiO5 (YSO), Ca2Al2SiO7 (CAS) and SrY4(SiO4)3O (SYS). The 2F7/2 splitting is particularly large in these materials and favourable to a quasi-three-level laser operating scheme. Calculations performed using the point charge electrostatic model for these compounds and using a consistent set of effective atomic charges confirm the experimental results. This should permit to use this model in a predictive approach.

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Citations
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Journal ArticleDOI

Diode-pumped Yb:Sr(3)Y(BO(3))(3) femtosecond laser.

TL;DR: This is, to the authors' knowledge, the first mode-locked Yb:BOYS laser and the shortest duration obtained from an ytterbium laser with a crystalline host.
Journal ArticleDOI

Determination of laser parameters of ytterbium-doped oxide crystalline materials

TL;DR: In this paper, spectroscopic and laser properties at ∼ 1 µm of seven new ytterbium-doped crystalline materials (silicates Y 2SiO5, Ca2Al2SiO7,SrY4(SiO4)3O, borates Ca3Y2(BO3)4,Ca3Gd2(Bo3)2,SR3Y(BO 3)3, and Ba3Lu(BO)3)3 ) were investigated.
Journal ArticleDOI

Structural, spectroscopic, and tunable laser properties of Yb3+-doped NaGd(WO4)2

TL;DR: In this article, continuous-wave Yb 3+ -laser operation was studied at room temperature both under Ti:sapphire and diode laser pumping, and a maximum slope efficiency of 77% with respect to the absorbed power was achieved for the polarization by Ti:Sapphire laser pumping in a three-mirror cavity with Brewster geometry.
Journal ArticleDOI

Crystal growth, Yb3+ spectroscopy, concentration quenching analysis and potentiality of laser emission in Ca1−XYbXF2+X

TL;DR: In this paper, the Yb3+ concentration dependence of the experimental decay time was analyzed by using concentration gradient fiber in order to understand involved concentration quenching mechanisms in Ca1−XYbXF2+X crystals.
Journal ArticleDOI

Polyoxometalate-supported Y- and YbIII-hydroxo/oxo clusters from carbonate-assisted hydrolysis.

TL;DR: Control experiments show that carbonate not only functions in the hydrolysis of Y or Yb(III) ions, it also influences the structure of the complexes by complexation to yttrium and the f-block elements.
References
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Journal ArticleDOI

Evaluation of absorption and emission properties of Yb/sup 3+/ doped crystals for laser applications

TL;DR: In this paper, the emission and absorption properties of numerous host crystals doped with Yb/sup 3+/ ions have been studied, and the results are discussed in the framework of requirements for an effective diode-pumped Yb-sup-3+/ laser system.
Journal ArticleDOI

Pulsed laser operation of Yb-doped KY(WO 4 ) 2 and KGd(WO 4 ) 2

TL;DR: Spectroscopic properties and laser performance of Y b-doped tungstates at pulsed Ti:sapphire laser pumping are reported.
Journal ArticleDOI

A scalar crystal field strength parameter for rare-earth ions : meaning and usefulness

TL;DR: In this paper, the meaning of a scalar crystal field strength parameter defined previously [4, 5] is studied and it is shown why, in many cases, it can be used as an indication of the magnitude of the maximum Stark splitting of J-terms for ions in crystals of different structures and site symmetries.
Journal ArticleDOI

Ytterbium-doped Ca 4 GdO(BO 3 ) 3 : an efficient infrared laser and self-frequency doubling crystal

TL;DR: In this paper, a new ytterbium-doped crystal, Ca4GdO(BO3)3 (Yb:GdCOB), was proposed as a substitute for their widely used neodymium counterparts for infrared laser emission.
Journal ArticleDOI

Growth and evaluation of ytterbium-doped yttrium aluminum borate as a potential self-doubling laser crystal

TL;DR: In this paper, a doped nonlinear optical crystal, ytterbium: yttrium aluminum borate, Yb3+:YAl3(BO3)4, has been grown with good optical quality in a high-temperature solution from K2Mo3O10 and B2O3 fluxes.
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