Journal ArticleDOI
STERICALLY INDUCED, SPONTANEOUS COBALT-CARBON BOND HOMOLYSIS AND β-ELIMINATION REACTIONS OF PRIMARY AND SECONDARY ORGANOCOBALAMINS
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This article is published in ChemInform.The article was published on 2002-05-01. It has received 72 citations till now. The article focuses on the topics: Homolysis & Cobalt.read more
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Journal ArticleDOI
Enzymology of the acetyl-CoA pathway of CO2 fixation.
TL;DR: The remarkable series of enzymatic steps involved in acetyl-CoA formation by this pathway that is a key component of the global carbon cycle is described.
Journal ArticleDOI
Vitamin B12 catalysed reactions
TL;DR: This tutorial review concisely describes cobalamin-catalysed organic reactions that hold promise for environmentally friendly cobalt catalysis, leaving the reader with basic knowledge and the ability to harness the catalytic potential of this fascinating molecule.
Journal ArticleDOI
Determination and significance of transition metal-alkyl bond dissociation energies
Journal ArticleDOI
Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation
TL;DR: A mechanistic model of the reaction is advanced through the use of reaction progress kinetic analysis (RPKA), radical clock experiments, and stoichiometric studies, concluding that the reaction proceeds through an unprecedented alkylcobalt to nickel direct transmetalation.
Journal ArticleDOI
Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes.
Hui Cao,Yulong Kuang,Xiangcheng Shi,Koi Lin Wong,Boon Beng Tan,Jeric Mun Chung Kwan,Xiaogang Liu,Jie Wu +7 more
TL;DR: A combination of decatungstate and a cobaloxime catalyst for the photocatalytic dehydrogenative alkenylation of alkanes and aliphatic aldehydes with aryl alkenes in the absence of any external oxidant is reported.
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