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Structural inorganic chemistry

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The article was published on 1945-01-01 and is currently open access. It has received 5804 citations till now.

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Oxidative desulfurization and denitrogenation of a light gas oil using an oxidation/adsorption continuous flow process

TL;DR: In this article, the authors compared the oxidation reactivity of dibenzothiophene (DBT), 4,6-dimethyldibenzethiophene and trimethy-ldibenothiophena (C 3 -DBT) in light gas oil.
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Preparation and characterization of activated carbons from coconut shell impregnated with phosphoric acid

TL;DR: A series of activated carbons was prepared from coconut shell impregnated with phosphoric acid using a one-step carbonization procedure and varying conditions in order to optimize preparation parameters as discussed by the authors.
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Selective oxidative dehydrogenation of butane over VMgO catalysts

TL;DR: Vanadium-magnesium oxides were found to be active and selective catalysts for the oxidative dehydrogenation of propane to propene as mentioned in this paper, achieving a selectivity of up to 65% at 10% conversion, but decreased with increasing conversion.
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Pyrite oxidation and reduction: Molecular orbital theory considerations

TL;DR: In this article, molecular orbital theory is used to explain a heterogeneous reaction mechanism for both pyrite oxidation and reduction, and the mechanism demonstrates that the oxidation of FeS2 by Fe(3+) may occur as a result of three important criteria: (1) the presence of a suitable oxidant having a vacant orbital (in case of liquid phase) or site (solid phase) to bind to the FS2 via sulfur; (2) the initial formation of a persulfido (disulfide) bridge between FeS 2 and the oxidant, and (
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Solvothermal synthesis of perovskites and pyrochlores: crystallisation of functional oxides under mild conditions

TL;DR: The aim is to show how the synthesis of dense, mixed-metal oxide materials, usually prepared using the high temperatures associated with solid-chemistry, is perfectly feasible from solution in one step reactions, typically at temperatures as low as 200 °C, and that important families of oxide materials have now been reported to crystallise using such synthetic approaches.