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Structural inorganic chemistry

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The article was published on 1945-01-01 and is currently open access. It has received 5804 citations till now.

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Cyanide-bridged assemblies constructed from capped tetracyanometalate building blocks [MA(ligand)(CN)4]1−/2− (MA = Fe or Cr)

TL;DR: In this article, the magnetic properties of metal-cyanide assemblies are discussed in terms of the magnetic exchange coupling between MA and metal ions, and the most appealing single-chain magnets (SCMs) are the ferromagnetically coupled 2,4-ribbon like chains which exhibit slow magnetic relaxation and hysteresis effects.
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Effects of symmetry breaking in finite quantum systems

TL;DR: In this paper, a review of symmetry breaking and symmetry transformations in finite quantum systems is presented, with an emphasis on the peculiarities of the symmetry breaking in finite mesoscopic systems.
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Solar absorber coatings based on CoCuMnOx spinels prepared via the sol-gel process: structural and optical properties

TL;DR: In this paper, a spinel spinel structure with the composition CoCuMnOx-II was studied with X-ray diffraction (XRD), infrared (IR) absorbance and near-grazing incidence angle (NGIA) reflection-absorption spectroscopy.
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Librational Modes of Crystal Water in Hydrated Solids

TL;DR: In this paper, the authors present a review of the up-to-date information and understanding on the topic of librational modes of water in hydrated solids, focusing on the development of methodology and systematics.
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Zinc chloride and zinc bromide complexes—III: Structures of species in solution

TL;DR: Raman spectra of aqueous solutions containing zinc chloride or zinc bromide and of extracts into tri-n-butyl phosphate (TBP) have been obtained.