Journal ArticleDOI
Structural studies on actinides carboxylates—III Preparation, properties and crystal structure of lithium glutarate hydrogenglutarate dioxouranate(VI)tetrahydrate UO2(C5H6O4)Li(C5H7O4)·4H2O
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TLDR
The synthesis, thermal behaviour and crystal structure of lithium glutaratehydrogenglutaratedioxouranate (VI) tetrahydrate was described in this article, where the carboxylic groups were chelated on the uranium and monodentate on the lithium.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1979-01-01. It has received 39 citations till now. The article focuses on the topics: Tetrahydrate & Uranyl.read more
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Book ChapterDOI
X-ray structural analyses of organolithium compounds
TL;DR: In this article, the X-ray structural analyses of organolithium compounds have been discussed, and a number of mixed-metal organometallic compounds with a single contact between lithium and a carbon atom have been characterized.
Journal ArticleDOI
The crystal chemistry of uranium carboxylates
TL;DR: In this article, a comprehensive review of the crystal structures resulting from the different types of complexation of uranium with carboxylic acid molecules (excepting oxalate ligand) and their classification as a function of the nuclearity of identified building units is presented.
Journal ArticleDOI
Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)
TL;DR: Two novel uranyl adipates are reported as synthesized via hydrothermal treatment of uranium oxynitrate and adipic acid and contains a previously unreported [(UO(2))(2)O(8)] building unit cross-linked into a neutral metal-organic framework topology with vacant channels.
Journal ArticleDOI
Crystal Engineering with the Uranyl Cation I. Aliphatic Carboxylate Coordination Polymers: Synthesis, Crystal Structures, and Fluorescent Properties
TL;DR: In this paper, four novel coordination polymers, UO2(C7H10O4) (1), UO 2C8H12O4 (2) and UO 3C10H16O4(4), were synthesized from UO(NO3)2·6H2O and aliphatic dicarboxylic acids (pimelic, suberic, azelaic, and sebacic acids, respectively) using hydrothermal techniques and were characterized by single-crystal diffraction.
Journal ArticleDOI
Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)
TL;DR: A series of uranyl and lanthanide mellitate (trivalent Ce, Nd) mellitates (mel) has been hydrothermally synthesized in aqueous solvent, and Mixtures of these 4f and 5f elements revealed the formation of a rare case of Lanthanide-uranyl coordination polymers.
References
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Journal ArticleDOI
X-ray scattering factors computed from numerical Hartree–Fock wave functions
D. T. Cromer,J. B. Mann +1 more
TL;DR: In this paper, the Hartree-Fock wave function was used to compute X-ray scattering factors for neutral atoms from He to Lw and for most of the chemically significant ions through Lu3+ through Lu 3+.
Journal ArticleDOI
Relativistic Calculation of Anomalous Scattering Factors for X Rays
Don T. Cromer,David A. Liberman +1 more
TL;DR: In this paper, relativistic calculations of the photoelectric cross section have been made and the integral for the principal contribution to Δf′ has been evaluated numerically without approximation to the form of the cross section-vs-energy curve, as has been done in previous calculations.
Journal ArticleDOI
Coherent X‐Ray Scattering for the Hydrogen Atom in the Hydrogen Molecule
TL;DR: In this paper, the x-ray form factors for a bonded hydrogen in the hydrogen molecule have been calculated for a spherical approximation to the bonded atom, and the corresponding complex scattering factors have also been calculated.
Journal ArticleDOI
The infra-red absorption bands associated with the COOH and COOD groups in dimeric carboxylic acid—II: The region from 3700 to 1500 cm−1
S. Bratož,D. Hadži,N. Sheppard +2 more
TL;DR: In this article, the authors investigated the infra-red spectra of a number of dimeric carboxylic acids and their deutero (COOD) analogues in the region of 3700 to 1500 cm−1.
Journal ArticleDOI
Crystal chemical studies of the 5f-series of elements. XXV. The crystal structure of sodium uranyl acetate
TL;DR: In this paper, the positions of all atoms were deduced from precisely measured x-ray-diffraction intensities, and a revised bond length versus bond strength curve for U/sup VI/-O bonds was presented.