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Study on mechanical properties and microstructure of the new grouting material

Junwu Xia, +2 more
- Vol. 439, Iss: 4, pp 042047
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TLDR
In this article, the effects of different w/b ratios, curing ages, limes and SiO2 on the compressive strength of the new grouting material were investigated.
Abstract
The new grouting material with advantages of early strength, strong liquidity, better expansibility and environmental protection can be applied to underground structure engineering. The effects of different w/b ratios, curing ages, limes and SiO2 on the compressive strength of the new grouting material were investigated. By SEM and TGA-DSC analysis, its microscopic morphology and hydration products are explored. The results show that the early strength of the new grouting material develops rapidly, and the 3d compressive strength can reach 80% of the 28d compressive strength. Under the condition that the w/b ratio is 1.0, the compressive strength increases with CaO content in lime increasing. The addition of micron-SiO2 can improve compressive strength by about 5% when the formulation is reasonable. The main hydration products of SEM-EDS are needle-like ettringite, spherical aluminum gel and amorphous C-S-H(C-A-S-H) gel, corresponding to three endothermic peaks appearing in TGA-DSC at around 90°C, 230°C and 660 °C, respectively.

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Journal ArticleDOI

The Relationship between Compressive Strength and Pore Structure of the High Water Grouting Material

Abstract: To elucidate the relationship between compressive strength and pore structure of the high water grouting material with different water-binder ratios and CaO contents, the compressive strength was tested while pore structure including pore characteristic parameters and pore diameter distribution were investigated by BET, MIP, and 3D-XRM. Moreover, the evolution of hydration products was observed by TGA and SEM, illustrating the reactive mechanism of the material. Furthermore, the grey correlation coefficients between compressive strength and pore structure parameters were illustrated according to the grey correlation theory. The results show that CaO content in lime is proportional to the compressive strength with the water-binder ratio of 1.0 or 1.5, while the inverse trend appears with the water-binder ratio of 2.0. The high water grouting material belongs to the macropore material with the pores mainly within 100 nm to 2 μm. Its hydration products contain ettringite crystals, aluminum gels, and C-S-H gels. The productions of the hydration products are positively correlated with its compressive strength. In addition, the compressive strength of the high water grouting material is closely related to the pore characteristic parameters and the pore size distribution, especially the porosity, the most probable pore diameter, and the pore volumes within 100~500 nm and 10~100 nm.
Journal ArticleDOI

Experimental Study on the Influence of PVA Content on the Performance of Grouting Material in Deep Stope

TL;DR: In this paper, the effect of polyvinyl alcohol (PVA) content on the performance of fly ash-based cement grouting materials was investigated based on laboratory experiments, and the test results showed that the addition of PVA has limited effect on the initial and final setting time and brings a certain but minor delay on the appearance of the hydration peak period.
References
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Journal ArticleDOI

Calorimetric and thermogravimetric study on the influence of calcium sulfate on the hydration of ye’elimite

TL;DR: In this article, the hydration kinetics and the hydrated phase assemblages of the main hydraulic phase ye'elimite with calcium sulfate were studied by isothermal conduction calorimetry, thermogravimetric analysis, X-ray diffraction analysis and thermodynamic modelling.
Journal ArticleDOI

Activation of fly ash cementitious systems in the presence of quicklime: Part I. Compressive strength and pozzolanic reaction rate

TL;DR: In this paper, the effect of industrially produced quicklime on the strength development and pozzolanic reaction rates of different fly ash/cement (FC) systems was investigated.
Journal ArticleDOI

Development of microfine cement grouts by pulverizing ordinary cements

TL;DR: In this article, three different cements (CEM I, CEM II/B-M and CEM IV/B according to EN 197-1) containing 0, 23.5% and 38% of pozzolan, respectively, were pulverized to obtain three additional gradations from each cement, with nominal maximum grain sizes of 40, 20 and 10μm.
Journal ArticleDOI

Hydration of calcium sulphoaluminate clinker with additions of different calcium sulphate sources

TL;DR: In this article, the hydrated phases evolution of cementitious systems based on CSA clinker, mainly composed by ye'elimite (C4A3$) phase, blended with two calcium sulphate forms (i.e. gypsum and anhydrite) has been investigated.
Journal ArticleDOI

Activation of Fly Ash Cementitious Systems in the Presence of Quicklime. Part II: Nature of Hydration Products, Porosity and Microstructure Development

TL;DR: In this paper, a 2-part series study on the activating effect of industrial quicklime upon different fly ashes, concluding on its beneficial role by focusing on the nature of hydration products, pore size, and microstructure evolution of each system studied.
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