Journal ArticleDOI
Supramolecular Catalysis in Metal–Ligand Cluster Hosts
Casey J. Brown,F. Dean Toste,Robert G. Bergman,Robert G. Bergman,Kenneth N. Raymond,Kenneth N. Raymond +5 more
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This article is published in Chemical Reviews.The article was published on 2015-04-21. It has received 887 citations till now. The article focuses on the topics: Supramolecular catalysis & Ligand.read more
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A supramolecular microenvironment strategy for transition metal catalysis
David M. Kaphan,David M. Kaphan,Mark D. Levin,Robert G. Bergman,Robert G. Bergman,Kenneth N. Raymond,Kenneth N. Raymond,F. Dean Toste,F. Dean Toste +8 more
TL;DR: A hollow supramolecular capsule captured a gold or platinum complex and induced rapid bond formation between the carbon atoms in methyl groups bound to the metal, which could open the door to a wide range of chemical transformations that are currently held up by slow eliminations.
Journal ArticleDOI
Functional Capsules via Subcomponent Self-Assembly
TL;DR: How fundamental investigations into the host-guest chemistry of capsules prepared through subcomponent self-assembly have led to the design of useful functions and new applications is highlighted.
Journal ArticleDOI
Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage
William Cullen,M. Cristina Misuraca,Christopher A. Hunter,Nicholas H. Williams,Michael D. Ward +4 more
TL;DR: A new example (catalysis of the Kemp elimination reaction of benzisoxazole with hydroxide to form 2-cyanophenolate) in the cavity of a water-soluble M8L12 coordination cage, with two features of particular interest.
Journal ArticleDOI
Photophysical Properties of Organoplatinum(II) Compounds and Derived Self-Assembled Metallacycles and Metallacages: Fluorescence and its Applications
TL;DR: Using steady state and time-resolved-spectroscopic techniques and quantum computations in concert, it is determined that the emissive properties stem from the ligand-centered transitions involving π-type molecular orbitals with modest contributions from the metal-based orbitals.
Journal ArticleDOI
Chemical reactivity under nanoconfinement
TL;DR: This Review surveys strategies to control chemical reactivity of species under different types of nanoconfinement, specifically highlighting examples of different nanocompartments that influence reactivity in similar ways.
References
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Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals
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Supramolecular Chemistry—Scope and Perspectives Molecules, Supermolecules, and Molecular Devices (Nobel Lecture)
TL;DR: Developments in molecular and supramolecular design and engineering open perspectives towards the realization of molecular photonic, electronic, and ionic devices that would perform highly selective recognition, reaction, and transfer operations for signal and information processing at the molecular level.
Journal ArticleDOI
Coordination assemblies from a Pd(II)-cornered square complex.
TL;DR: The last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd4 square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres.
Journal ArticleDOI
Functional Molecular Flasks : New Properties and Reactions within Discrete, Self-Assembled Hosts
TL;DR: This Review briefly highlights the various molecular flasks synthesized before focusing on their use as functional molecular containers--specifically for the encapsulation of guest molecules to either engender unusual reactions or unique chemical phenomena.
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