Journal ArticleDOI
Synthesis and characterization of extremely bulky amido-germanium(II) halide complexes
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TLDR
The extremely bulky aryl/silyl secondary amines, HN(Ar)(SiMe3), Ar = C6H2-i-Pr2(CPh3)-2,6,4 (LDipH), or C 6H2{C(H)Ph2}2, 6, 4 (Lt-BuH) have been synthesized.Abstract:
The extremely bulky aryl/silyl secondary amines, HN(Ar)(SiMe3), Ar = C6H2-i-Pr2(CPh3)-2,6,4 (LDipH), C6H2{C(H)Ph2}2-i-Pr-2,6,4 (L†H), or C6H2{C(H)Ph2}2-t-Bu-2,6,4 (Lt-BuH), have been synthesized vi...read more
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A Systematic Study of Structure and E-H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes.
Matthew Usher,Andrey V. Protchenko,Arnab Rit,Jesús Campos,Eugene L. Kolychev,Rémi Tirfoin,Simon Aldridge +6 more
TL;DR: The results of these reactivity studies imply that the use of the very strongly σ-donating boryl or silyl substituents is an effective strategy for rendering metallylene complexes competent for E-H bond activation.
Journal ArticleDOI
Extremely bulky amide ligands in main group chemistry
TL;DR: This review reports on the recent developments for three classes of sterically demanding, monodentate amide ligands with emphasis on their synthesis, structure and reactivity.
Journal ArticleDOI
Synthesis of Elusive Chloropnictenium Ions
TL;DR: This work describes the synthesis and full characterization of elusive chloropnictenium ion salts of the type [(R)Ar*N(SiMe)ECl][A] and the reactivity towards the Lewis base 4-dimethylaminopyridine was investigated.
Journal ArticleDOI
Intramolecular Metal⋅⋅⋅π-Arene Interactions in Neutral and Cationic Main Group Compounds.
TL;DR: The lithium and potassium amide salts showed different patterns of solvation and demonstrated that the SiPh3 substituent is able to be involved in stabilizing the electrophilic metal.
References
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N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands.
Journal ArticleDOI
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium
Roland Fischer,Philip P. Power +1 more
TL;DR: The key unifying feature of almost all molecules discussed in this review is that they are generally stabilized by the use of bulky substituents which block associative or various decomposition pathways.