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Synthesis and properties of polyimide–clay hybrid

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TLDR
A polyimide hybrid with montmorillonite clay mineral has been synthesized from a dimethylacetamide (DMAC) solution of poly(amic acid) and a DMAC dispersion of montmoroniite intercalated with an ammonium salt of dodecylamine as mentioned in this paper.
Abstract
A polyimide hybrid with montmorillonite clay mineral has been synthesized from a dimethylacetamide (DMAC) solution of poly(amic acid) and a DMAC dispersion of montmorillonite intercalated with an ammonium salt of dodecylamine. Montmorillonite consists of stacked silicate sheets about 2000 A in length, 10 A in thickness. In this hybrid, montmorillonite is dispersed homogeneously into the polyimide matrix and oriented parallel to the film surface. Thanks to this special structure, this hybrid showed excellent gas barrier properties. Only 2 wt % addition of montmorillonite brought permeability coefficients of various gases to values less than half of those of ordinary polyimide. Furthermore, this hybrid had low thermal expansion coefficient. © 1993 John Wiley & Sons, Inc.

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Synthesis and characterization of poly(styrene-maleic anhydride)-montmorillonite nanocomposite

TL;DR: In this article, a poly(styrene-maleic anhydride)-montmorillonite nanocomposites were prepared by intercalation of layered polymer ions with the polymer ions.
Journal ArticleDOI

The influence of platelet disorientation on the barrier properties of composites: a numerical study

TL;DR: In this paper, the relationship between the platelet orientational distribution and the overall effective barrier properties (gas permeability) of mineral filled composites was investigated, and numerical estimates quantifying the difference between the barrier properties of composites with fully aligned and randomly oriented platelets were presented.
Journal ArticleDOI

Preparation, characterization, and properties of poly(vinyl chloride)/organophilic-montmorillonite nanocomposites

TL;DR: In this article, the effect of OMMT content on the nanostructures and properties of nanocomposites was studied by wide angle X-ray diffraction and transmission electron microscopy (TEM).
Patent

Organo-titanate catalysts for preparing pure macrocyclic oligoesters

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Molecular Dynamics Study of the Intercalation of Diblock Copolymers into Layered Silicates

TL;DR: In this paper, a simulation of the flow of a symmetric diblock copolymer from a bulk melt into a slit whose surfaces are modified by grafted surfactant chains, and whose walls are maintained at a constant pressure to permit the slit to open as polymer intercalates, is presented.
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