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Synthesis and properties of polyimide–clay hybrid

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TLDR
A polyimide hybrid with montmorillonite clay mineral has been synthesized from a dimethylacetamide (DMAC) solution of poly(amic acid) and a DMAC dispersion of montmoroniite intercalated with an ammonium salt of dodecylamine as mentioned in this paper.
Abstract
A polyimide hybrid with montmorillonite clay mineral has been synthesized from a dimethylacetamide (DMAC) solution of poly(amic acid) and a DMAC dispersion of montmorillonite intercalated with an ammonium salt of dodecylamine. Montmorillonite consists of stacked silicate sheets about 2000 A in length, 10 A in thickness. In this hybrid, montmorillonite is dispersed homogeneously into the polyimide matrix and oriented parallel to the film surface. Thanks to this special structure, this hybrid showed excellent gas barrier properties. Only 2 wt % addition of montmorillonite brought permeability coefficients of various gases to values less than half of those of ordinary polyimide. Furthermore, this hybrid had low thermal expansion coefficient. © 1993 John Wiley & Sons, Inc.

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Journal ArticleDOI

Formation and properties of nylon-6 and nylon-6/montmorillonite composite nanofibers

TL;DR: In this paper, the effects of organically modified montmorillonite (O-MMT) layers on the properties of the nylon-6 solution and electrospun nanocomposite fibers were investigated.
Journal ArticleDOI

Viscoelastic properties and thermal degradation kinetics of silica/PMMA nanocomposites

TL;DR: In this paper, three organic silica groups, two modified with methyl groups and the third an octane, made these inorganic silica particles more hydrophobic and exhibited higher storage and loss moduli than those of pristine PMMA.
Patent

Polymer nanocomposites comprising a polymer and an exfoliated particulate material derivatized with organo silanes, organo titanates and organo zirconates dispersed therein and process of preparing same

TL;DR: In this article, a process of forming a composite material comprising a polymer matrix comprising a polymeric material and dispersed particles selected from the group consisting of platelet or fibrillar particles having average thicknesses of less than 50 A and a maximum thickness of more than 100 A and fibrils having an average diameter equal to or less than about 200 A and having an organo metallic residue species covalently bonded to said particles.
Journal ArticleDOI

Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites

TL;DR: In this article, the morphology and thermal stabilization mechanism of polymeric nanocomposites prepared by solution intercalation of linear low density polyethylene (LLDPE) with montmorillonite (MMT), MgAl layered double hydroxide (LDH), and ZnAl LDH have been studied by X-ray diffraction (XRD), transmission electron microscopy (TEM), dynamic Fourier transform infrared (FTIR) spectroscopy, and thermogravimetric analysis (TGA).
Journal ArticleDOI

The fabrication of syndiotactic polystyrene/organophilic clay nanocomposites and their properties

TL;DR: In this paper, the fabrication of nanocomposite of syndiotactic polystyrene (sPS)/organophilic clay was conducted by melt intercalation, where various amorphous styrenic polymers were introduced during the melt mixing process.
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