Journal ArticleDOI
Synthesis and single-crystal x-ray study of the mononuclear dihapto-benzyne (dehydrobenzene) nickel(0) complex Ni(.eta.2-C6H4)[(C6H11)2PCH2CH2P(C6H11)2]. Insertion reactions with simple molecules and x-ray crystal structure of the nickelaindan complex Ni(CH2CH2C6H4-o)[(C6H11)2PCH2CH2P(C6H11)2]
About:
This article is published in Organometallics.The article was published on 1985-11-01. It has received 70 citations till now. The article focuses on the topics: Crystal structure & Single crystal.read more
Citations
More filters
Journal ArticleDOI
[2+2+2] Cycloaddition Reactions Catalyzed by Transition Metal Complexes
Pramod R. Chopade,Janis Louie +1 more
TL;DR: In this article, the general mechanistic aspects of the [2+2++2] cycloaddition reaction are discussed along with the proposed models of asymmetric induction.
Journal ArticleDOI
Homogeneous-catalytic reactions of carbon dioxide with unsatureated substrates, reversible CO2-carriers and transcarboxylation reactions
Journal ArticleDOI
Metal Complexes of Small Cycloalkynes and Arynes
TL;DR: Cyclooctyne is the smallest unsubstituted cycloalkyne that can be isolated in the free state and it is more reactive than acyclic alkynes towards transition metal complexes.
Journal ArticleDOI
Preparation of benzyne complexes of group 10 metals by intramolecular suzuki coupling of ortho-metalated phenylboronic esters: molecular structure of the first benzyne-palladium(0) complex.
Mikael Retbøll,Alison J. Edwards,A. David Rae,Anthony C. Willis,Martin A. Bennett,Eric Wenger +5 more
TL;DR: This reaction can be regarded as an intramolecular version of a Suzuki cross-coupling reaction, the driving force for which may be the steric interaction between the boronic ester group and the phosphine ligands present in the precursors 2 and 3.
Journal ArticleDOI
Mechanistic Studies of Transition-Metal-Catalyzed [2 + 2 + 2] Cycloaddition Reactions.
TL;DR: This review covers the mechanistic aspects of the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction involving all kinds of unsaturated substrates with metals such as Co, Ni, Ru, Rh, Ir, Pd, Zr, Ti, Ta, and Nb.