Synthesis of a Zircon-Cadmium Sulfo Selenide Pigment by a Sol-Gel Technique
TLDR
In this article, it was shown that the relative volume of zircon to cadmium sulfo-selenide has an important role on the complete encapsulation of colorants and the quality of pigment.Abstract:
Preparation of fire red cadmium sulfo- selenide pigments based on zircon via solid-state reactions encountered with some difficulties. Undesirable reactivity and inadequate homogeneity of components are two important problems, which counteracted on completely covering of color agents by zirconium silicate and so stable production of these materials. It has shown that by using a sol-gel method the above-mentioned problem will be eliminated and a desirable color shade can be obtained. In the sol-gel process, at first a precipitatant was prepared by mixing of Se (dissolved in sodium sulfide solution) and a cadmium sulfate-zirconium acetate solution. Gelation was occurred by adding a diluted sodium silicate solution into the washed and dried precipitant. The mineralizer was lithium fluoride, which was added to the washed/dried gel. Calcinations of the later compound were done at about 950°C. The experiments showed that the relative volume of zircon to cadmium sulfo selenide has an important role on a complete encapsulation of colorants and so on quality of pigment. According to our experiment, the optimum relative volume of colorant agent to zircon was determined as bout 40/60.read more
Citations
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Synthesis and application of C@ZrSiO4 inclusion ceramic pigment from cotton cellulose as a colorant
TL;DR: In this article, a zircon-based black pigment, which consists of in-situ carbon transformed from cotton cellulose as core and Zircon as shell (C@ZrSiO 4 ), was prepared via non-hydrolytic sol-gel (NHSG) method.
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Enhanced high temperature oxidization resistance of silica coated γ-Ce 2 S 3 red pigments
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Preparation and chromatic properties of C@ZrSiO4 inclusion pigment via non-hydrolytic sol–gel method
TL;DR: In this article, a zirconium silicate coated carbon (C@ZrSiO4) black pigment was prepared via a non-hydrolytic sol-gel (NHSG) process.
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Preparation of silica encapsulated carbon black with high thermal stability
TL;DR: In this article, a silica encapsulated carbon black has been prepared by a modified emulsion polymerization, which shows high oxidation resistance up to 1200°C and good stability in frit glaze at 950°C.
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Modeling and evaluation for encapsulation efficiency of zircon-based heteromorphic encapsulation pigments
TL;DR: In this article, the authors established a heteromorphic encapsulation modeling upon series of hypotheses and preconditions and correspondingly proposed a theoretical function αmax = [1−−(k+1)(D/L)]3 for encapsulation efficiency evaluation.
References
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Enthalpy of Formation of Zircon
TL;DR: In this article, the authors used high-temperature solution calorimetry in molt 2PbO {center dot} B{sub 2}O{sub 3] to determine the enthalpy of reaction of the formation of zircon from its constituent oxides.
Reference EntryDOI
Colorants for Ceramics
TL;DR: In this paper, the various factors that must be addressed before selecting a pigment include processing stability, uniformity and reproducibilty, particle size, dispersibility, and compatibility.
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Reaction of Zirconia with Silica at the Stoichiometry of Zircon
TL;DR: In this paper, Zirconia was combined with silica and halide mineralizers and fired in a nitrogen atmosphere, and X-ray analysis showed that zircon was formed, demonstrating that an oxygen atmosphere is not necessary for the formation of ZIRcon.