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Journal ArticleDOI

Synthesis of molecular chains: phenylene thioether and sulfoxide oligomers

José Vicente, +2 more
- 30 Jun 2008 - 
- Vol. 64, Iss: 27, pp 6281-6288
TLDR
In this article, a general synthetic approach to synthesize molecular chains is reported. It is based on a step-by-step method each consisting first in a Pd-catalyzed reaction between ArI and HXAr′Br (Ar=aryl, Ar′=arylene) to give ArXAr-I that can be reacted with HXAR′Br in the following step.
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This article is published in Tetrahedron.The article was published on 2008-06-30. It has received 17 citations till now.

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Advances in Synthetic Applications of Hypervalent Iodine Compounds

TL;DR: One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.
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Diamine ligands in copper -catalyzed reactions

TL;DR: The use of diamine-based ligands has been important in these advances and in this review we discuss these systems, including the choice of reaction conditions and applications in the synthesis of pharmaceuticals, natural products and designed materials as mentioned in this paper.
Journal ArticleDOI

Magnetically Separable CuFe2O4 Nanoparticles Catalyzed Ligand-Free CS Coupling in Water: Access to (E)- and (Z)-Styrenyl-, Heteroaryl and Sterically Hindered Aryl Sulfides

TL;DR: This procedure provides an easy access to useful and challenging biologically active organosulfides which are difficult to achieve by other methods and excellent stereoselectivity has been observed for styrenyl sulfides.
Journal ArticleDOI

Oxidoreductive coupling of thiols with aryl halides catalyzed by copper on iron

TL;DR: Synthesis and utilization of a simple copper on iron catalyst in the coupling of aryl halides with thiols through disulfide intermediate is reported and ensures reductive media for the coupling.
Journal ArticleDOI

Metal-Mediated Halogen Exchange in Aryl and Vinyl Halides: A Review.

TL;DR: Remarkably efficient processes have been developed for metal-mediated halogen exchange in aryl and vinyl halides: they are overviewed, in a comprehensive manner, in this review article.
References
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Modern Synthetic Methods for Copper‐Mediated C(aryl) ? O, C(aryl) ? N, and C(aryl) ? S Bond Formation

TL;DR: In this article, the authors highlight the recent developments in the copper-mediated (both stoichiometric and catalytic) reactions of aryl boronic acids as reaction partners in both O- and N-arylation.
Journal ArticleDOI

Functional liquid-crystalline assemblies: self-organized soft materials.

TL;DR: New approaches to the functionalization of liquid crystals are described and it is shown how the design ofliquid crystals formed by supramolecular assembly and nano-segregation leads to the formation of a variety of new self-organized functional materials.
Journal ArticleDOI

Polymer Therapeutics: Concepts and Applications

TL;DR: An overview of polymer therapeutics is presented with a focus on concepts and examples that characterize the salient features of the drug-delivery systems.
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