Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance
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This review discusses advances in synthetic organic electrochemistry since 2000 with enabling methods and synthetic applications analyzed alongside innate advantages as well as future challenges of electroorganic chemistry.Abstract:
Electrochemistry represents one of the most intimate ways of interacting with molecules. This review discusses advances in synthetic organic electrochemistry since 2000. Enabling methods and synthetic applications are analyzed alongside innate advantages as well as future challenges of electroorganic chemistry.read more
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Journal ArticleDOI
Electrifying Organic Synthesis
Anton Wiebe,Anton Wiebe,Tile Gieshoff,Sabine Möhle,Eduardo Rodrigo,Michael Zirbes,Siegfried R. Waldvogel,Siegfried R. Waldvogel +7 more
TL;DR: This Review surveys recent developments in electrochemical synthesis that will influence the future of this area and examines the role of stoichiometric reagents in this area.
Journal ArticleDOI
Electrochemical strategies for C-H functionalization and C-N bond formation.
TL;DR: This review provides an overview on the use of anodic electrochemical methods for expediting the development of carbon-hydrogen functionalization and carbon-nitrogen bond formation strategies and aims to provide inspiration for future synthetic applications in the field of electrosynthesis.
Journal ArticleDOI
Chemistry with Electrochemically Generated N-Centered Radicals
Peng Xiong,Hai-Chao Xu +1 more
TL;DR: A unique feature of electrochemistry is the simultaneous occurrence of anodic oxidation and cathodic reduction, which allows the dehydrogenative transformations to proceed through H2 evolution without the need for chemical oxidants.
Journal ArticleDOI
Electrochemical Arylation Reaction.
TL;DR: The electrochemical formation of the aryl-substrate bond is discussed for aromatic substrates, heterocycles, other multiple bond systems, and even at saturated carbon substrates.
Journal ArticleDOI
Mechanistic Studies in Photocatalysis
TL;DR: The discussion will use selected case studies to highlight how mechanistic investigations can be instrumental in guiding the invention and development of synthetically useful photocatalytic transformations.
References
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Journal ArticleDOI
Cu(II)-Catalyzed Functionalizations of Aryl C−H Bonds Using O2 as an Oxidant
TL;DR: These newly discovered reaction conditions are also applicable for cyanation, amination, etherification, and thioetherification of aryl C-H bonds.
Journal ArticleDOI
Redox catalysis in organic electrosynthesis: basic principles and recent developments.
Robert Francke,R. Daniel Little +1 more
TL;DR: Progress is described in the field of electroorganic synthesis, a process that can be accomplished more efficiently and purposefully using modern computational tools, and summarizes recent advances.
Journal ArticleDOI
Modern Strategies in Electroorganic Synthesis
TL;DR: Electrochemical Properties of scCO2 2285 5.1.
Journal ArticleDOI
Organic electrosynthesis: a promising green methodology in organic chemistry
Bernardo A. Frontana-Uribe,R. Daniel Little,Jorge G. Ibanez,Agustín Palma,Ruben Vasquez-Medrano +4 more
TL;DR: In this article, the main characteristics of electrochemistry as a promising green methodology for organic synthesis are described and exemplified, and their relationship with the twelve green chemistry principles is described.
Journal ArticleDOI
Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method
TL;DR: In this Outlook, illustrative examples of electrochemical reactions in the context of the synthesis of complex molecules are highlighted, showcasing the intrinsic benefits of electro chemical reactions versus traditional reagent-based approaches.
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Redox catalysis in organic electrosynthesis: basic principles and recent developments.
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