Journal ArticleDOI
Systematic development of high bandwidth, low drive voltage organic electro-optic devices and their applications
Reads0
Chats0
TLDR
In this article, organic electro-optic (EO) materials have been presented that exhibit EO coefficients in the range of 60-100 pm/V at the telecommunications wavelengths of 1.3 and 1.55 μm.About:
This article is published in Optical Materials.The article was published on 2003-01-01. It has received 67 citations till now. The article focuses on the topics: Insertion loss.read more
Citations
More filters
Journal ArticleDOI
Electric field poled organic electro-optic materials: state of the art and future prospects.
Journal ArticleDOI
High-Q Optical Resonators in Silicon-on-Insulator-Based Slot Waveguides
TL;DR: In this paper, the design, fabrication and characterization of high-Q oval resonators based on slot waveguide geometries in thin silicon-on-insulator material were described.
Journal ArticleDOI
Systematic study of the structure-property relationship of a series of ferrocenyl nonlinear optical chromophores.
Yi Liao,Bruce E. Eichinger,Kimberly A. Firestone,Marnie Haller,Jingdong Luo,Werner Kaminsky,Jason B. Benedict,Philip J. Reid,Alex K.-Y. Jen,Larry R. Dalton,Bruce H. Robinson +10 more
TL;DR: This work underscores the potential for Fc donor moieties, which have been underutilized, but also demonstrates that experimental characterization and theoretical simulations are now congruent, viable methods for assessing potential performance of NLO materials.
Journal ArticleDOI
Rational design of organic electro-optic materials
TL;DR: In this article, quantum mechanical calculations are used to optimize the molecular first hyperpolarizability of organic chromophores and statistical mechanical calculations were used to optimise the translation of molecular hyperp polarizability to macroscopic electro-optic activity (to values of greater than 100 pm V−1 at telecommunications wavelengths).
Journal ArticleDOI
Systematic Nanoengineering of Soft Matter Organic Electro-optic Materials†
Larry R. Dalton,Stephanie J. Benight,Lewis E. Johnson,Daniel B. Knorr,Ilya Kosilkin,Bruce E. Eichinger,Bruce H. Robinson,Alex K.-Y. Jen,René M. Overney +8 more
TL;DR: An overview of the development and utilization of organic electro-optic materials is presented with emphasis on the role played by quantum and statistical mechanical calculations in understanding critical structure/function relationships that have guided the improvement of such materials over the past two decades as discussed by the authors.
References
More filters
Journal ArticleDOI
Low (Sub-1-Volt) Halfwave Voltage Polymeric Electro-optic Modulators Achieved by Controlling Chromophore Shape
Yongqiang Shi,Cheng Zhang,Hua Zhang,James H. Bechtel,Larry R. Dalton,Larry R. Dalton,Bruce H. Robinson,William H. Steier +7 more
TL;DR: This study, together with recent demonstrations of exceptional bandwidths and ease of integration, demonstrates the potential of polymeric materials for next generation telecommunications, information processing, and radio frequency distribution.
Journal ArticleDOI
Demonstration of 110 GHz electro-optic polymer modulators
Datong Chen,Harold R. Fetterman,Antao Chen,William H. Steier,Larry R. Dalton,Wenshen Wang,Yongqiang Shi +6 more
TL;DR: In this paper, an external-cavity tunable semiconductor laser was used to detect the modulation signal at 1.3 µm using a laser heterodyne system.
Journal ArticleDOI
Low Vπ electrooptic modulators from CLD-1 : Chromophore design and synthesis, material processing, and characterization
TL;DR: In this paper, a ring-locked, phenyltetraene-based, second-order nonlinear optical chromophore (CLD-1) was synthesized.
Book ChapterDOI
Nonlinear Optical Polymeric Materials: From Chromophore Design to Commercial Applications
TL;DR: Polymeric electro-optic modulators can be operated for long periods of time at temperatures on the order of 100 °C as discussed by the authors, and the role of electrostatic interactions in influencing the choice of processing conditions is also discussed.
Journal ArticleDOI
Monte Carlo Statistical Mechanical Simulations of the Competition of Intermolecular Electrostatic and Poling-Field Interactions in Defining Macroscopic Electro-Optic Activity for Organic Chromophore/Polymer Materials†
TL;DR: In this article, Monte Carlo statistical mechanical computer simulations of the electric field poling of second-order nonlinear optical chromophores, characterized by large dipole moments, polarizabilities, and hyperpolarizabilities are presented.