Journal ArticleDOI
Tetrabutylammonium Decatungstate (Chemo)selective Photocatalyzed, Radical C ? H Functionalization in Amides
TLDR
In this article, photoamidation of electron-poor olefins has been achieved by means of a radical-induced C-H functionalization in amides, and Tetrabutylammonium decatungstate was used as photocatalyst of the reaction and allowed the smooth generation of different carboncentered radicals depending on the amide structure.Abstract:
Photoamidation of electron-poor olefins has been achieved by means of a radical-induced C-H functionalization in amides. Tetrabutylammonium decatungstate was used as photocatalyst of the reaction and allowed the smooth generation of different carbon-centered radicals depending on the amide structure.read more
Citations
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Journal ArticleDOI
Carbon-Carbon Bond Forming Reactions via Photogenerated Intermediates.
TL;DR: An overview of the current approaches for the photochemical and photocatalytic generation of reactive intermediates and their application in the formation of carbon-carbon bonds is offered, with particular attention to the most recent examples.
Journal ArticleDOI
Direct α-functionalization of saturated cyclic amines.
TL;DR: Methods for the direct α-functionalization of saturated cyclic amines are described and transition-metal-catalyzed reactions involving other intermediates have been treated as a separate and fourth class.
Journal ArticleDOI
Decatungstate as an efficient photocatalyst in organic chemistry.
TL;DR: Several new discoveries concerning the heterogenization of decatungstate for the development of sustainable methods with broad applications in catalysis, such as the photooxidation or photodegradation of various organic substrates, are presented.
Journal ArticleDOI
Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration
TL;DR: A comprehensive review of the synthetic applications of photocatalyzed d-HAT can be found in this article, where the authors provide a comprehensive overview of the main applications of PCHAT.
Journal ArticleDOI
Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope
Davide Ravelli,Maurizio Fagnoni,Takahide Fukuyama,Tomohiro Nishikawa,Ilhyong Ryu,Ilhyong Ryu +5 more
TL;DR: In this paper, the synergistic control of the SH2 transition states of hydrogen abstraction by polar and steric effects provides a promising strategy in achieving site-selective C(sp3)-H functionalization under decatungstate anion photocatalysis.
References
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Journal ArticleDOI
Photocatalysis for the formation of the C-C bond.
Journal ArticleDOI
Photocatalysis: a promising route for 21st century organic chemistry
TL;DR: This account shows how photocatalysis is offering an alternative green route for the production of organics through selective photocatalytic conversions.
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Photocatalysis with organized systems for the oxofunctionalization of hydrocarbons by O2.
Journal ArticleDOI
Copper-catalyzed coupling of amides and carbamates with vinyl halides.
TL;DR: A general and efficient copper-catalyzed method for the amidation of vinyl bromides and iodides has been developed and the double bond geometry of the vinyl halides was retained under the reaction conditions.
Journal ArticleDOI
1,1,1-tris(hydroxymethyl)ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols.
Yao-Jung Chen,Hsin-Hung Chen +1 more
TL;DR: This inexpensive and commercially available tripod ligand has been demonstrated to facilitate the copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols to afford the corresponding desired products in good to excellent yields.