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The AFm phase in Portland cement

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TLDR
In this article, a scheme of phase balances was proposed to calculate the mineralogical balances of a hydrated cement paste with greater accuracy than hitherto practicable, and experimentally-determined phase relationships were depicted at 25 deg. C.
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This article is published in Cement and Concrete Research.The article was published on 2007-02-01. It has received 604 citations till now. The article focuses on the topics: AFm phase & Portlandite.

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NOx sequestration by calcium aluminate cementitious materials

TL;DR: In this article, the authors quantified NOx uptake efficiency and explored NOx binding mechanisms in calcium aluminate cementitious (CAC) materials and showed that the permanent NOx absorption in CAC could be largely attributed to the chemical binding of converted NOx within aluminum-bearing phases.
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Solidification/stabilization of flue gas desulfurization brine and coal fly ash for heavy metals and chloride immobilization: Effects of S/S conditions and zero-valent-iron pretreatment

TL;DR: Quantitative X-ray diffraction and scanning electron microscopy analyses strongly indicated the formation of Friedel's salt, Ca2Al(OH)6(Cl,OH)·2H2O, is critical in the retainment of heavy metals and chloride in FGD wastewater and chloride.
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Modification on the chloride binding capacity of cementitious materials by aluminum compound addition

TL;DR: In this paper, the effects of aluminum compound on the binding of admixed chloride in cementitious materials were investigated, and three commonly available aluminum compounds, aluminum oxide, aluminum hydroxide and colloidal nano-alumina were applied.
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Chloride ion transport performance of lining concrete under coupling the action of flowing groundwater and loading

TL;DR: In this paper, the authors investigated the chloride ion transport behavior of lining concrete under the coupling action of flowing groundwater and loading and found that the damage layer thickness and chloride ion concentration of the lining concrete increases with the increase of erosion age.
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Reactivity Assessment of Modified Ferro Silicate Slag by R 3 Method

TL;DR: In this article, the reactivity of supplementary cementitious materials (SCMs) and their contribution to the hydration mechanism were measured from measured heat release, bound water content, and CH consumption.
References
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ReportDOI

User's guide to PHREEQC (Version 2)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations

TL;DR: PHREEQC as discussed by the authors is a C program written in the C programming language that is designed to perform a wide variety of low-temperature aqueous geochemical calculations.
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The Role of Calcium Carbonate in Cement Hydration

TL;DR: In this paper, it is shown by experiment and calculation that much, if not all, of this calcite is reactive and affects the distribution of lime, alumina and sulfate and thereby alters the mineralogy of hydrated cement pastes.
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Thermodynamic modelling of the hydration of Portland cement

TL;DR: In this paper, a thermodynamic model is developed and applied to calculate the composition of the pore solution and the hydrate assemblage during the hydration of an OPC.
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Nagra/PSI Chemical Thermodynamic Data Base 01/01

TL;DR: The Nagra/PSI Chemical Thermodynamic Data Base has been updated to support performance assessments of the planned Swiss repositories for radioactive waste as discussed by the authors, and more than 70% of the database contents have been revised.
Journal ArticleDOI

Thermodynamic investigation of the CaOAl2O3CaSO4H2O system at 25°C and the influence of Na2O

TL;DR: In this article, the CaOAl2O3CaSO4H2O system at 25°C has been investigated by calculations on the equilibrium solubility surfaces of AH3, C3AH6, CH, C 6 A S 3 H x, C 4 A S H x and gypsum.
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