Book ChapterDOI
The Binding and Activation of Carbon Monoxide, Carbon Dioxide, and Nitric Oxide and Their Homogeneously Catalyzed Reactions
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TLDR
In this article, the binding and activation of carbon monoxide, carbon dioxide, and nitric oxide by transition-metal complexes is discussed and the selected reactions of these molecules, which are catalyzed by metal complexes in solution.Abstract:
Publisher Summary This chapter discusses the binding and activation of carbon monoxide, carbon dioxide, and nitric oxide by transition-metal complexes and examines the selected reactions of these molecules, which are catalyzed by metal complexes in solution. These three simple oxides exhibit significantly different coordination chemistries and diverse reactivity patterns when bonded to transition-metal ions. The activation of each, thus poses different problems in the field of homogeneous catalysis. By considering these three simple inorganic oxides together, the chapter compares the similarities and differences apart from examining each independently. Homogeneously catalyzed reactions can be viewed as occurring in a sequence of steps, each of which involves a change in one or more of the following properties of the catalyst metal complex: coordination number, metal-ion oxidation state, and valence-electron count. Of these properties, the metal ion oxidation state seems most susceptible to confusion, especially with ligands, such as nitrosyl, π-bonded allyl, and bridging hydride.read more
Citations
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Journal ArticleDOI
Infrared spectroscopic identification of species arising from reactive adsorption of carbon oxides on metal oxide surfaces
Guido Busca,Vincenzo Lorenzelli +1 more
TL;DR: The usual assignments of absorption bands due to products of CO and CO2 reactive adsorption on metal oxide surfaces are also critically reexamined in this paper, where carbonate, bicarbonate and formate ions, and of CO2 in metal complexes are reported.
Journal ArticleDOI
Spectroscopic characterization of the acid properties of metal oxide catalysts
TL;DR: The use of different basic probe molecules whose IR spectra are sensitive to protonation and/or to the strength of Lewis acid-base interaction is described in this paper, where the results obtained for the characterization of the Lewis acid strength of more than 30 binary and ternary mixed oxides are interpreted on the basis of the different polarizing powers of the involved cations.
Journal ArticleDOI
Mitigation of CO2 by Chemical Conversion: Plausible Chemical Reactions and Promising Products
Xu Xiaoding,Jacob A. Moulijn +1 more
TL;DR: A critical literature analysis was conducted on the viable usage of CO2 in the framework of the attempts to reduce the emissions of CO 2 into the atmosphere from various processes or the rate of increase of the CO2 concentration in the atmosphere.
Journal ArticleDOI
Fourier transform infrared study of the adsorption and coadsorption of nitric oxide, nitrogen dioxide and ammonia on TiO2 anatase
TL;DR: In this article, the adsorption and coadsorption of NO, NO 2 and NH 3 on TiO 2 anatase has been studied by Fourier transform infrared (FT-IR) spectroscopy.
Journal ArticleDOI
On the bonding and reactivity of CO2 on metal surfaces
TL;DR: In this paper, the authors present ab-initio valence-bond calculations on free and coordinated CO 2, and three different coordination geometries for the CO 2 molecule are considered: (a) pure carbon coordination, (b) pure oxygen coordination, and (c) mixed carbon-oxygen coordination.
References
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Journal ArticleDOI
Principles of structure, bonding, and reactivity for metal nitrosyl complexes
Journal ArticleDOI
Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region
C. S. Kraihanzel,F. A. Cotton +1 more