Journal ArticleDOI
The Butler-Volmer equation in electrochemical theory: Origins, value, and practical application
TLDR
The use of the Butler-Volmer equation to describe electrode kinetics has been extensively studied in the literature, such as misuse of terminology or inappropriate mathematical expressions of the kinetic equations as mentioned in this paper.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 2020-09-01. It has received 108 citations till now. The article focuses on the topics: Butler–Volmer equation.read more
Citations
More filters
A new perspective on the electron transfer: Recovering the Butler--Volmer equation in non-equilibrium thermodynamics
TL;DR: Very general relations of Butler-Volmer structure are derived which are based on a rigorous non-equilibrium thermodynamic model and allow for adaption to a wide variety of electrochemical systems.
Journal ArticleDOI
Mass transport in PEM water electrolysers: A review
TL;DR: In this paper, the authors discuss the current knowledge related to mass transport and its characterisation/diagnosis for PEMWEs, considering the flow channels, liquid-gas diffusion layer, and polymer electrolyte membrane in particular.
Journal ArticleDOI
Single-Molecule Junction: A Reliable Platform for Monitoring Molecular Physical and Chemical Processes.
TL;DR: In this paper , the authors focus on the applications of single-molecule junctions in monitoring molecular physical and chemical processes, and propose some potential applications in this field, as well as discuss the open challenges of single molecule detection in the fields of physics and chemistry.
Journal ArticleDOI
Mass transport in PEM water electrolysers: A review
TL;DR: In this paper , the authors discuss the current knowledge related to mass transport and its characterisation/diagnosis for PEMWEs, considering the flow channels, liquid-gas diffusion layer, and polymer electrolyte membrane in particular.
Journal ArticleDOI
Electro–Chemo–Mechanical Failure of Solid Electrolytes Induced by Growth of Internal Lithium Filaments
TL;DR: In this paper , a multiphysics simulation aiming to investigate the evolution of the mechanical failure of the solid electrolyte induced by the internal growth of Li is reported, which enables examination of factors dominating the degradation process, including the geometry, number and size of Li filaments and voids in the electrolyte.
References
More filters
Book
Electrochemical Methods: Fundamentals and Applications
Allen J. Bard,Larry R. Faulkner +1 more
TL;DR: In this paper, the authors present a comprehensive overview of electrode processes and their application in the field of chemical simulation, including potential sweep and potential sweep methods, coupled homogeneous chemical reactions, double-layer structure and adsorption.
Journal ArticleDOI
The Activated Complex in Chemical Reactions
TL;DR: In this paper, the probability of the activated state is calculated using ordinary statistical mechanics, and the probability multiplied by the rate of decomposition gives the specific rate of reaction, and necessary conditions for general statistical treatment to reduce to the usual kinetic treatment are given.
Journal ArticleDOI
Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more
TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
Journal ArticleDOI
Modeling of Galvanostatic Charge and Discharge of the Lithium/Polymer/Insertion Cell
TL;DR: In this article, the galvanostatic charge and discharge of a lithium anode/solid polymer separator/insertion cathode cell is modeled using concentrated solution theory, which is general enough to include a wide range of polymeric separator materials, lithium salts, and composite insertion cathodes.
Book
Electrochemical Impedance Spectroscopy
TL;DR: In this paper, the authors provide guidelines for experimental design, discuss the relevance of accuracy contour plots to wiring and instrumentation selection, and emphasize the importance of the Kramers-Kronig relations to data validation and analysis.