Journal ArticleDOI
The Chemistry of the Fullerenes: An Overview
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This article is published in Angewandte Chemie.The article was published on 1993-08-01. It has received 209 citations till now. The article focuses on the topics: Fullerene.read more
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[60]Fullerene chemistry for materials science applications
TL;DR: In this article, the basic principles of the organic chemistry of fullerenes, together with a description of the physicochemical properties that have made these carbon cages popular in materials science, and review the most recent achievements in functionalization of the original fullerene aimed at the creation of new molecular materials.
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Polymers containing fullerene or carbon nanotube structures
TL;DR: A review of polymeric fullerenes and carbon nanotubes can be found in this paper, where a number of functional polymers have been used to react with fullerene and CNTs.
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Buckybowls: Polynuclear Aromatic Hydrocarbons Related to the Buckminsterfullerene Surface
Peter W. Rabideau,Andrzej Sygula +1 more
TL;DR: The synthesis, chemistry, and properties of curved-surface, polynuclear aromatics would be of great interest even if buckminsterfullerene had not been discovered as discussed by the authors.
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In vivo studies of fullerene-based materials using endohedral metallofullerene radiotracers
TL;DR: The present findings demonstrate the feasibility of using water-solubilized metallofullerene radiotracers to monitor the fate of fullerene-based materials in animals, and suggest that water- solvent-based fullerenes, in general, may be useful components in drug design.
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Kleider machen Leute: Heck-Reaktion im neuen Gewand†
Armin de Meijere,Frank E. Meyer +1 more
TL;DR: The Heck-Reaktion as discussed by the authors is an example of a reaktion-based substrate with unsymmetrisch mehrfach substituierten Reaktionspartnern.
References
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Solid C60: a new form of carbon
TL;DR: In this article, a new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules.
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Organic molecular soft ferromagnetism in a fullerene c60.
Pierre-Marc Allemand,K. C. Khemani,A. Koch,Fred Wudl,Karoly Holczer,Steven Donovan,George Grüner,Joe D. Thompson +7 more
TL;DR: The properties of an organic molecular ferromagnet with a Curie temperature of 16.1 kelvin are described, where the ferromagnetic state shows no remanence, and the temperature dependence of the magnetization below ;Tc does not follow the behavior expected of a conventional ferromaagnet.
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Efficient production of C60 (buckminsterfullerene), C60H36, and the solvated buckide ion
R. E. Haufler,J. Conceicao,L. P. F. Chibante,Y. Chai,N. E. Byrne,Scott Flanagan,Michael M. Haley,Sean C. O'Brien,C. Pan +8 more
TL;DR: Buckminsterfullerene, C{sub 60}, was prepared in gram quantities by contact-arc vaporization of a graphite rod in a 100-Torr atmosphere of helium, followed by extraction of the resultant graphite soot with toluene as discussed by the authors.
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Electrochemical detection of C606- and C706-: Enhanced stability of fullerides in solution
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Radical reactions of c60.
TL;DR: The radical adducts with n = 3 and 5 are stable above 50�C and have been identified by electron spin resonance (ESR) spectroscopy as the allylic R3C60 and cyclopentadienyl R5C60 radicals.