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The effect of hydrogen codeposition on the morphology of copper electrodeposits. I. The concept of effective overpotential

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TLDR
In this paper, the effect of hydrogen codeposition on the morphology of copper electrodeposits was studied and the dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and the average current efficiencies of the evolved hydrogen were derived from them.
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This article is published in Journal of Electroanalytical Chemistry.The article was published on 2006-03-01. It has received 191 citations till now. The article focuses on the topics: Hydrogen & Overpotential.

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Citations
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Hierarchical Nanostructures: Design for Sustainable Water Splitting

TL;DR: In this article, the authors introduce the utilization of hierarchical nanostructures in electrocatalytic and photo-electrochemical applications and focus on the synthetic strategies of attaining these hierarchical structures as well as to demonstrate their corresponding mechanisms for performance improvement.
Journal ArticleDOI

Building with bubbles: the formation of high surface area honeycomb-like films via hydrogen bubble templated electrodeposition

TL;DR: An overview of the status of the DHBT technique is presented, highlighting preparation techniques and emerging applications.
Journal ArticleDOI

Electrodeposition of three-dimensional porous silver foams

TL;DR: In this paper, the deposition of Ag porous foams from a novel electrolyte, using hydrogen bubbles as a template during deposition at high cathodic currents, is described using NH 4 + to increase the hydrogen evolution rate, foams with an average pore size of 20-45μm were produced.
Journal ArticleDOI

Direct electrodeposition of nanoporous gold with controlled multimodal pore size distribution

TL;DR: In this article, a fast one-step preparation of high-surface area nanoporous gold with a multimodal pore size distribution is proposed, and the meta-stability of the material's morphology is examined.
Journal ArticleDOI

Poly-Amide Modified Copper Foam Electrodes for Enhanced Electrochemical Reduction of Carbon Dioxide

TL;DR: In this article, a strategy to modulate the electrocatalytic activity of copper toward CO2 reduction involving adsorption of acrylamide, acrylic acid, and allylamine polymers is presented.
References
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Book

Modern Aspects of Electrochemistry

TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
Book

Fundamental Aspects of Electrometallurgy

TL;DR: In this article, the current distribution in electrochemical cells is analyzed and the optimum conditions for electroplating and surface finishing of metal electrodeposits are discussed. But the authors do not consider the problem of metal deposition without an external current.
Journal ArticleDOI

The effect of electrolytically evolved gas bubbles on the thickness of the diffusion layer

TL;DR: In this article, the authors investigated the mechanism determining the mass transfer at a gas evolving electrode, and determined the thickness of the Nernst diffusion layer as a function of the current density for both hydrogen and oxygen evolving on horizontal and vertical electrodes in acid as well as in alkaline solutions.
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