Journal ArticleDOI
The electrogenerated chemiluminescence of pyrene and some related compounds
TLDR
In this paper, the characteristics of the electrogenerated chemiluminescence in dimethylformamide of pyrene, 1,2-benzpyrene, 3,4-benzinpyrene and dibenzo[a,lpyrene] generated with optimum conditions of applied potential are described.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1971-03-01. It has received 20 citations till now. The article focuses on the topics: Pyrene & Emission spectrum.read more
Citations
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Journal ArticleDOI
Electrogenerated Chemiluminescence and Its Biorelated Applications
TL;DR: ECL has now become a very powerful analytical technique and been widely used in the areas of immunoassay, food and water testing, and biowarfare agent detection and has also been successfully exploited as a detector of flow injection analysis (FIA), high-performance liquid chromatography (HPLC), capillary electrophoresis, and micro total analysis (μTAS).
Journal ArticleDOI
Circularly-Polarized Electrochemiluminescence from a Chiral Bispyrene Organic Macrocycle.
Francesco Zinna,Silvia Voci,Lorenzo Arrico,Elodie Brun,Alexandre Homberg,Laurent Bouffier,Tiziana Funaioli,Jérôme Lacour,Neso Sojic,Lorenzo Di Bari +9 more
TL;DR: The first observation of circular polarization of electrochemiluminescence (ECL) from a purely organic derivative is reported and is the first step towards the molecular engineering of tailored dyes that can act as both ECL and CP-ECL reporters for (bio)analysis.
Journal ArticleDOI
Electrogenerated chemiluminescence detection of single entities
TL;DR: The development of ECL intensity and imaging based single entity detection is reviewed and emphasis on the assays of small entities including single molecules, micro/nanoparticles and cells is placed on.
Journal ArticleDOI
Efficient and Stable Blue Electrogenerated Chemiluminescence of Fluorene‐Substituted Aromatic Hydrocarbons
TL;DR: Among various ECL active materi-als, polyaromatic hydrocarbons were the earliestsubjects of ECL studies, and stable, long-lived radical ions in solution uponoxidation and reduction.
Journal ArticleDOI
Electrogenerated Chemiluminescence. 74. Photophysical, Electrochemical, and Electrogenerated Chemiluminescent Studies of Selected Nonplanar Pyrenophanes
Rebecca Y. Lai,James J. Fleming,Brad L. Merner,Rudolf J. Vermeij,Graham J. Bodwell,Allen J. Bard +5 more
TL;DR: In this paper, the photophysical, electrochemical, and electrogenerated chemiluminescent studies of four new pyrenophanes were performed and it was shown that the nonplanarity in these compounds resulted in a substantial decrease in fluorescence quantum yield as well as a slight red shift in both the absorption and emission spectra.
References
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Journal ArticleDOI
On the Theory of Chemiluminescent Electron‐Transfer Reactions
TL;DR: In this article, a mechanism for chemiluminescent electron transfer reactions was described for very exothermic homogeneous electron exchange reactions, and it was shown that the intersection of the potential energy surface of the reactants with that of electronically unexcited products occurs only at high energies.
Journal ArticleDOI
Excimer fluorescence spectra of pyrene derivatives
J. B. Birks,L.G. Christophorou +1 more
TL;DR: In this paper, the effect of concentration on the fluorescence spectra of solutions of pyrene and its derivatives was investigated, and the mechanism involved in this effect was discussed, as well as its mechanism.
Journal ArticleDOI
Excimer Formation and Emission via the Annihilation of Electrogenerated Aromatic Hydrocarbon Radical Cations and Anions
Journal ArticleDOI
Electrogenerated chemiluminescence. I. Mechanism of anthracene chemiluminescence in N,N-dimethylformamide solution
Larry R. Faulkner,Allen J. Bard +1 more
TL;DR: Chandross, Longworth, and Viscoz as discussed by the authors showed that the emission spectrum comprises two or more components, the spectral distribution of the component shortest in wavelength is similar to that of anthracene fluorescence, but the others are broad, structureless, and located toward the red with respect to the first component.
Related Papers (5)
Electrogenerated chemiluminescence. VI. Efficiency and mechanisms of 9,10-diphenylanthracene, rubrene, and pyrene systems at a rotating-ring-disk electrode
J. T. Maloy,Allen J. Bard +1 more