Journal ArticleDOI
The formation of dinucsear μ-hydroxo-cobalt(III) complexes
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TLDR
The acidity constants of the deprotonated triaminocyclohexane have been determined with a rapid flow apparatus as mentioned in this paper, but it proved to be impossible to study the slow condensation to polynuclears quantitatively because of decomposition with production of ammonia.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1971-07-01. It has received 27 citations till now. The article focuses on the topics: Triol & Stability constants of complexes.read more
Citations
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Journal ArticleDOI
Neue μ-Hydroxo-Übergangsmetallkomplexe, I. Darstellung und Struktur des trans-Diaqua-di-μ-hydroxo-bis[(1,4,7-triazacyclononan)cobalt(III)]-Kations; Kinetik und Mechanismus seiner Bildung
TL;DR: In this paper, a mechanism for the first hydroxo-bridge cleavage of the triply-bridged complex was proposed, involving cis-trans isomerization of 2 as the rate determining step.
Book ChapterDOI
Hydroxo-Bridged Complexes of Chromium (III), Cobalt (III), Rhodium (III), and Iridium (III)
TL;DR: In this paper, a review of the chemistry of hydroxo-bridged chromium(III), cobalt(III) and rhodium-III complexes is presented.
Journal ArticleDOI
Hydrolysis of the Organometallic Aqua Ion fac-Triaquatricarbonylrhenium(I). Mechanism, pKa, and Formation Constants of the Polynuclear Hydrolysis Products
André Egli,Kaspar Hegetschweiler,Alberto Roger Ariel,Ulrich Abram,Roger Schibli,Roman Hedinger,Volker Gramlich,and Reinhard Kissner,P. August Schubiger +8 more
TL;DR: In this paper, the hydrolytic pathways of the organometallic aqua ion [Re(CO)3(H2O)3]+ in aqueous media were investigated by means of potentiometric titration experiments.
Journal ArticleDOI
Structure and Reactivity of a Dinuclear Cobalt(III) Complex with a Bridging Phosphate Monoester
TL;DR: In this article, the bidentate monoester (2-H) was converted to tridentate inorganic phosphate (3) using the crystal structure of an analog of 2-H.
Journal ArticleDOI
Synthesis, Structure, and DNA Cleavage Properties of Copper(II) Complexes of 1,4,7-Triazacyclononane Ligands Featuring Pairs of Guanidine Pendants
TL;DR: Two new ligands, L(1) and L(2), have been prepared via N-functionalization of 1,4,7-triazacyclononane with pairs of ethyl- or propyl-guanidine pendants, suggesting some degree of cooperativity between the copper center and guanidinium pendants in the hydrolysis of the phosphate ester linkages of DNA.
References
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Journal ArticleDOI
A Spectrophotometric Study of the Hydrolysis of Iron(III) Ion. II. Polynuclear Species1
Ronald M. Milburn,W. C. Vosburgh +1 more
Journal ArticleDOI
Metal Ammine Formation in Aqueous Solution. VIII. Acid-base, cis-trans, and complex equilibria in the cobalt(III)-ethylenediamine system.
Journal ArticleDOI
Zur Kenntnis der Zweikernigen Co(III)-Ammine mit Hydroxo-Brücken
M. Linhard,H. Siebert +1 more
TL;DR: In this paper, the perchlorates of Di-μ-diacido-Komplexes were firstly prepared in aqueous solution and the equilibrium between the tri-mh-hydroxo and the di-mdiaquo complex was studied.
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