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The key role of peripheral substituents in the chemistry of phthalocyanines and their analogs

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TLDR
The preparation and optical properties of peripherally substituted phthalocyanines and their analogs have been widely discussed in this paper, and a review highlights methodologies that have been published in poorly known and mostly unavailable Russian journals.
Abstract
The preparation and optical properties of peripherally substituted phthalocyanines and their analogs (i.e. naphthalocyanines, anthracyanines, aza-analogs of phthalocyanines, and tetraazaporphyrins) have been widely discussed. This review highlights methodologies that have been published in poorly known and mostly unavailable Russian journals.

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Citations
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A set of highly water-soluble tetraethyleneglycol-substituted Zn(II) phthalocyanines: synthesis, photochemical and photophysical properties, interaction with plasma proteins and in vitro phototoxicity

TL;DR: Evidence is provided for the relevance of the non-peripherally substituted derivative of three Zn(II) phthalocyanines substituted by hydroxyl-terminated tetraethylene glycol chains for in vivo investigations of type II-photosensitisers for photodynamic therapy.
Journal ArticleDOI

Electrochemical and spectroelectrochemical characterization of newly synthesized manganese, cobalt, iron and copper phthalocyanines

TL;DR: In this paper, a tetra-substituted phthalocyanine core with 3,4-(dimethoxyphenylthio) moieties at peripheral positions was synthesized and characterized by FT-IR, mass spectroscopy, and electronic spectrum analysis.
Journal ArticleDOI

Long-range electronic communication in free-base meso-poly(ferrocenyl)-containing porphyrins.

TL;DR: Analysis of intervalence charge-transfer bands observed in the NIR region for all mixed-valence complexes suggests electron localization and thus class II behavior in the Robin-Day classification.
Journal ArticleDOI

Layer-by-layer construction of graphene/cobalt phthalocyanine composite film on activated GCE for application as a nitrite sensor

TL;DR: In this paper, a novel graphene/cobalt phthalocyanine composite film was prepared by layer-by-layer (LBL) technique which for the first time used the activated positively charged glassy carbon electrode (A-GCE) as the substrate.
References
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Book

Phthalocyanines : properties and applications

TL;DR: In this paper, the most recent research on the fundamental and applied chemistry of the phthalocyanine derivatives is presented in a detailed and comprehensive way, including their redox character, essential to many of their potential industrial applications.
Journal ArticleDOI

Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage

TL;DR: This tutorial review describes recent research directed towards the synthesis of polymer-based organic microporous materials termed Polymers of Intrinsic Microporosity (PIMs), and demonstrates the potential of PIMs for heterogeneous catalysis and hydrogen storage.
Book

Chemical Aspects of Photodynamic Therapy

TL;DR: The chemistry of Haematoporphyrin Derivative (HpD) and second generation photosensitisers are discussed in this paper, as well as other examples of photodynamic therapy.
Journal ArticleDOI

Molecular Materials by Self‐Assembly of Porphyrins, Phthalocyanines, and Perylenes

TL;DR: A review of some recent efforts to construct highly ordered assemblies of porphyrins, phthalocyanines, and perylenes by means of self-assembly in solution and on surfaces, and by attaching them to polymeric scaffolds is given in this paper.
Journal ArticleDOI

Phthalocyanines: from outstanding electronic properties to emerging applications.

TL;DR: The description of the latest attempts at incorporating phthalocyanines into photovoltaic devices for solar energy conversion and onto quantum dots for photodynamic therapy or quantum computing is described.
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