Journal ArticleDOI
The mechanism of asymmetric homogeneous hydrogenation. Rhodium(I) complexes of dehydroamino acids containing asymmetric ligands related to bis(1,2-diphenylphosphino)ethane
John M. Brown,Penny A. Chaloner +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1980-04-01. It has received 102 citations till now. The article focuses on the topics: Rhodium.read more
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Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs
Pablo Etayo,Anton Vidal-Ferran +1 more
TL;DR: An updated overview of the most striking contributions in rhodium-catalysed asymmetric hydrogenation of diverse alkene classes is provided, organised according to substrate class: acrylate derivatives, itaconate derivatives,α-substituted enamides, α-arylenol acetates, and minimally functionalised olefins.
Journal ArticleDOI
Recent advances in biaryl-type bisphosphine ligands
TL;DR: Biaryl-type bisphosphine ligands of recent vintage and their effective applications to asymmetric syntheses are reviewed in this paper, where 155 references are provided for bisphphosphines.
Journal ArticleDOI
2, 2'-bis(diphenylphosphino)-1, 1'-binaphthyl(binap)
TL;DR: Racemic 2, 2'-bis(diphenylphosphino)-l, 1'-binaphthyl has been synthesized from 2 2, 2'-dihydroxy-l, l'-biosphine in two steps and resolved into optically pure (R)-(+) and (S) (-) enantiomers by the use of (+)-di-μ-chlorobis[(S)-N,N-dimethyl-α-phenylethylamine-2C,N]dipalladium.
Journal ArticleDOI
Asymmetric hydrogenation catalyzed by first-row transition metal complexes
TL;DR: In this paper, a comprehensive view of the application of first-row transition metals in asymmetric hydrogenation and asymmetric transfer hydrogenation is provided, and a mechanism-oriented and focused on catalytic systems are discussed.
Journal ArticleDOI
Das Isoinversionsprinzip ‐ ein allgemeines Selektionsmodell in der Chemie
TL;DR: In this article, the chiralitatsubertragung bei chemischen Reaktionen with stochiometrisch or katalytisch verwendeten chiralen Auxiliaren wird heute haufig und erfolgreich praktiziert.
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Asymmetric hydrogenation of methyl (Z)-.alpha.-acetamidocinnamate catalyzed by [1,2-bis(phenyl-o-anisoyl)phosphino)ethane]rhodium(I): kinetics, mechanism and origin of enantioselection
Clark R. Landis,Jack Halpern +1 more