Journal ArticleDOI
The palladium assisted transfer reduction of. alpha. ,. beta. -unsaturated nitroalkenes to oximes using ammonium formate
TLDR
In this article, β-Unsaturated nitroalkenes are readily reduced to the corresponding oximes in good yields using ammonium formate in the presence of palladium.About:
This article is published in Synthetic Communications.The article was published on 1990-01-01. It has received 80 citations till now. The article focuses on the topics: Ammonium formate & Palladium.read more
Citations
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Journal ArticleDOI
Transforming Nano Metal Nonselective Particulates into Chemoselective Catalysts for Hydrogenation of Substituted Nitrobenzenes
Pedro Serna,Avelino Corma +1 more
TL;DR: In this paper, three generations of gold nanoparticles on solid supports have been developed to improve the performance of the original gold catalysts in the presence of double and triple CC bonds, with H2 as reductant and no soluble additives needed.
Journal ArticleDOI
Applications of bismuth(III) compounds in organic synthesis
TL;DR: This review article summarizes the applications of bismuth(III) compounds in organic synthesis since 2002 and is largely organized by the reaction type although some reactions can be placed in multiple sections.
Journal ArticleDOI
Solid state deoximation with ammonium persulfate-silica gel: Regeneration of carbonyl compounds using microwaves
TL;DR: Ammonium persulfate on silica gel rapidly regenerates carbonyl compounds from their corresponding oxime derivatives using microwaves under solventless "dry" conditions as discussed by the authors.
Journal ArticleDOI
Solid state regeneration of ketones from oximes on wet silica supported sodium periodate using microwaves
TL;DR: Microwave irradiation of ketoximes on wet silica supported sodium periodate under solvent-free conditions provides a fast, efficient and simple method for regeneration of ketones as mentioned in this paper.
Journal ArticleDOI
A mild and efficient method for cleavage of CN using Mg(HSO4)2 in the presence of wet SiO2
Farhad Shirini,Mohammad Ali Zolfigol,B. Mallakpour,Shadpour Mallakpour,Abdol R. Hajipour,I. M. Baltork +5 more
TL;DR: Mg(HSO 4 ) 2 in the presence of wet SiO 2 was reacted with oximes, hydrazones and semicarbazones and converted them to the corresponding carbonyl compounds in good to high yields under mild and heterogeneous conditions.
References
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Journal ArticleDOI
Heterogeneous catalytic transfer hydrogenation and its relation to other methods for reduction of organic compounds
TL;DR: In this paper, a review of transfer reduction using hydrogen donors is presented, focusing mainly on those processes that can be effected by heterogeneous catalysis using molecules other than molecular hydrogen as the source of hydrogen.
Journal ArticleDOI
Catalytic Transfer Hydrogenation
TL;DR: In this paper, the authors present an overview of the potential applications of structural selectivity in the field of Synthetic Synthetic Applications (Synthetic Applications IV. Mechanism V. Summary and Prospects V I, References
Book
Reductions in organic chemistry
TL;DR: In this article, the authors present a list of the most commonly used methods of reducing a mixture of different types of Heterocyclic Aromatic Heterocyclic Substitution Derivatives of Esters.
Journal ArticleDOI
Nuclear magnetic resonance spectroscopy. Use of carbon-13 spectra to establish configurations of oximes
TL;DR: In this article, the use of C nmr spectra for the determination of configurations of oximes is described, and the problems of quantitative analysis of syn-anti mixtures of oxime by cmr, because of differential T_1 and Overhauser effects, are considered.