Journal ArticleDOI
The problem of feed-back in solid-state chemistry
TLDR
In this paper, the authors deal with some of the assumtions and limitations of classical models used in thermal analysis kinetic studies of solid-state rections, and propose a new model based on non-classical models.Abstract:
The paper deals with some of the assumtions and limitations of ‘classical’ models used in thermal analysis kinetic studies of solid-state rections.read more
Citations
More filters
Journal ArticleDOI
Mechanically Responsive Molecular Crystals
TL;DR: This paper presents a meta-analyses of the chiral stationary phase of the H2O/O2 mixture and shows clear trends in the direction of increasing chiral insensitivity to Naumov’s law.
Journal ArticleDOI
Mechanochemistry of inorganic and organic systems: what is similar, what is different?
TL;DR: The aim of this contribution is to provide an overview of the basic concepts of mechanochemistry in relation to inorganic and organic systems.
Journal ArticleDOI
Size effects in chemistry of heterogeneous systems
TL;DR: In this paper, the size effects in single component and multicomponent solid-phase systems are discussed, and the results of studies of the properties of nanocomposites and nanoparticles are discussed.
Journal ArticleDOI
Grundlagen der thermischen analysetechniken und ihre anwendungen in der praparativen chemie
Heiko K. Cammenga,Matthias Epple +1 more
TL;DR: In this article, the authors describe the Grundlagen der Thermischen Analyse methoden and an ausgewahlten, nicht Vollstandigkeit anstrebenden Beispielen ihre Anwendungen auf nieder and hochmolekulare Stoffe vorgestellt werden.
Journal ArticleDOI
Accommodation of the actual solid-state process in the kinetic model function
Nobuyoshi Koga,Haruhiko Tanaka +1 more
TL;DR: In this paper, the degree of coordination between the kinetic information from the thermonalytical measurements and the kinetic theory of the solid-state reactions was investigated through the microscopic study of the thermal dehydration of several inorganic salt hydrates.
References
More filters
BookDOI
Thermophysical properties of polymers
TL;DR: In this article, the authors describe thermodynamic behavior of solid polymers in plastic deformation and cold drawing, and thermal behavior of soft polymers under fracture, as well as experimental methods and instrumentation.
Journal ArticleDOI
Thermal analysis kinetics-problems, pitfalls and how to deal with them
TL;DR: In this paper, the authors discuss the limitations of one's reasonable expectations for the theoretical significance and empirical application of derived kinetics parameters, and caveats concerning overly simple and "canned" techniques of analysis of kinetics data are given.
Journal ArticleDOI
Philosophy of non-isothermal kinetics
TL;DR: The most debatable and discrepant viewpoints of non-isothermal kinetics are discussed in the form of twelve questions and answers as discussed by the authors, including the reputation of nonisothermal analysis when carried out by thermoanalysts, the consequences of simplified concepts transferred from the kinetics of homogeneous reactions, the physical meaning of basic kinetic parameters in solid-state processes, the kinetic compensative effect and interdependence of kinetic parameters using the Arrhenius rate constant, the mutual usefulness of differential and integral methods of kinetic data evaluation, their accuracy and correctness, the reliability of