Journal ArticleDOI
The uses of pincer complexes in organic synthesis
Reads0
Chats0
About:
This article is published in Tetrahedron.The article was published on 2003-03-10. It has received 576 citations till now. The article focuses on the topics: Organic synthesis & POCOP.read more
Citations
More filters
Journal ArticleDOI
Transition metal-catalyzed direct arylation of substrates with activated sp3-hybridized C-H bonds and some of their synthetic equivalents with aryl halides and pseudohalides.
Fabio Bellina,Renzo Rossi +1 more
TL;DR: New, effective, and more environmentallybenignmethodologiesfortheformation of(cyclo)alkyl-aryl bonds, which require a reduced number of synthetic operations, have emerged as valuable alternatives to the conventional cross-coupling reactions.
Journal ArticleDOI
Bond Activation and Catalysis by Ruthenium Pincer Complexes
TL;DR: The heterolytic activation of dihydrogen by NH/H2 MLC was reported by Fryzuk and co-workers in 1987 with pincer Ir and Rh complexes, and complex 73 was found to be an active dehydrogenation catalyst for ammoniaborane and hydrogenation reactions as discussed below.
Journal ArticleDOI
Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends
TL;DR: Kinetic investigations have identified the coordination compound 207 as a common intermediate of Calkyl-H and the Caryl-Calkyl bond activation, and suggest steric factors to play a more dominant role than electronic differences in determining the C-C vs C-H selectivity.
Journal ArticleDOI
Palladacycles in catalysis – a critical survey
TL;DR: The application of palladacycles as catalysts for cross-coupling and similar reactions is reviewed in this article, where the advantages and limitations of palladiacycle catalysts are discussed.
References
More filters
Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
Journal ArticleDOI
Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998
TL;DR: The palladium-catalyzed cross-coupling reaction between organoboron compounds and organic halides or triflates provides a powerful and general methodology for the formation of carbon-carbon bonds as discussed by the authors.
Journal ArticleDOI
Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts
Martin Albrecht,Gerard van Koten +1 more
TL;DR: This review discusses the synthetic methodologies that are currently available for the preparation of platinum group metal complexes containing pincer ligands and especially emphasizes different applications that have been realized in materials science such as the development and engineering of sensors, switches, and catalysts.
Journal ArticleDOI
Recent Developments and New Perspectives in the Heck Reaction
Walter Cabri,Ilaria Candiani +1 more
Related Papers (5)
Cyclometalated phosphine-based pincer complexes: Mechanistic insight in catalysis, coordination, and bond activation
Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts
Martin Albrecht,Gerard van Koten +1 more