Journal ArticleDOI
The vibrational spectra of simple cobalt(III) and chromium(III) ammine complexes
TLDR
In this paper, the laser Raman spectral data for solid [Co(NH3)6]X3 (where X = Cl, Br and I), [Co[NH3]5Cl]Cl2, cis-and trans-[Co[Co( NH3)4Cl2]Cl, and the sulfate and pentachlororocuprate (II) of Cr(NH 3)63+, together with Raman spectra of aqueous solutions of Co[NH 3]63+ and Co[CoAbout:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 1970-07-01. It has received 18 citations till now. The article focuses on the topics: Raman spectroscopy.read more
Citations
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Journal ArticleDOI
Vibrational spectra and force constants of pure ammine complexes
K.H. Schmidt,Achim Müller +1 more
Journal ArticleDOI
Skeletal vibrational spectra, force constants, and bond properties of transition metal ammine complexes
K. H. Schmidt,A. Mueller +1 more
Journal ArticleDOI
Observation of surface‐enhanced Raman scattering for transition‐metal hexaammine cations at the outer Helmholtz plane: Implications for enhancement mechanisms at electrochemical interfaces
TL;DR: In this paper, surface-enhanced Raman scattering (SERS) has been observed at silver electrodes for several transition metal hexaammine complexes even though these cations cannot bind to the metal surface and are excluded from the electrochemical inner layer by the presence of a monolayer of chloride or bromide anions.
Journal ArticleDOI
Vibrational spectra and pseudo-exact force constants of [Ni(NH3)6]2+, [Zn(NH3)4]2+, and [Zn(CN)4]2− with 58Ni/62Ni, 64Zn/68Zn and H/D isotopic substitution
TL;DR: In this paper, it was shown that reasonable force constants for the skeletons of hexammine and tetrammine metal complexes can be calculated from Raman and infrared data of the isotopically substituted ions using the point mass model, if the isotope shifts can be measured accurately.
Journal ArticleDOI
Phase transition and molecular motions in [Cr(NH3)6](BF4)3 studied by differential scanning calorimetry, infrared spectroscopy and X-ray diffraction
TL;DR: The phase transition in [Cr(NH 3 ) 6 ](BF 4 ) 3 at T c h =238.42 K and T c c c =237.93 K was determined by differential scanning calorimetry (DSC) as mentioned in this paper.
References
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Journal ArticleDOI
Infrared Spectra and Force Constants of Ammine Complexes
Journal ArticleDOI
Spectres de vibration et fréquences fondamentales de composés de co-ordination hexamminés
TL;DR: In this article, the fundamental vibrations of these compounds have been determined and their frequencies calculated with a modified Urey-Bradley field of force, the influence of the nature of the central metal and of the associated anion is discussed.
Journal ArticleDOI
Reflectance spectrum and electronic states of the CuCl53- ion in a number of crystal lattices
Geoffrey C. Allen,Noel S. Hush +1 more
Related Papers (5)
Schwingungsspektroskopische untersuchung von hexamminkobalt(III)- und -chrom(III)-salzen
Hans Siebert,Hans H. Eysel +1 more