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TiO 2 -Coated Carbon Nanotube-Silicon Solar Cells with Efficiency of 15%

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TLDR
CNT-Si junction solar cells with efficiencies reaching 15% are reported by coating a TiO2 antireflection layer and doping CNTs with oxidative chemicals, resulting in much enhanced short-circuit current and external quantum efficiency.
Abstract
Combining carbon nanotubes (CNTs), graphene or conducting polymers with conventional silicon wafers leads to promising solar cell architectures with rapidly improved power conversion efficiency until recently. Here, we report CNT-Si junction solar cells with efficiencies reaching 15% by coating a TiO2 antireflection layer and doping CNTs with oxidative chemicals, under air mass (AM 1.5) illumination at a calibrated intensity of 100 mW/cm2 and an active device area of 15 mm2. The TiO2 layer significantly inhibits light reflectance from the Si surface, resulting in much enhanced short-circuit current (by 30%) and external quantum efficiency. Our method is simple, well-controlled, and very effective in boosting the performance of CNT-Si solar cells.

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Journal ArticleDOI

Recent Development of Carbon Nanotube Transparent Conductive Films

TL;DR: This Review provides a comprehensive analysis of carbon nanotube transparent conductive films covering detailed fabrication methods including patterning of the films, chemical doping effects, and hybridization with other materials.
Journal ArticleDOI

Colloidal Antireflection Coating Improves Graphene–Silicon Solar Cells

TL;DR: The antireflection treatment was realized by a simple spin-coating process, which significantly increased the short-circuit current density and the incident photon-to-electron conversion efficiency to about 90% across the visible range.
Journal ArticleDOI

Engineering graphene and TMDs based van der Waals heterostructures for photovoltaic and photoelectrochemical solar energy conversion

TL;DR: The physics of band alignment, the chemistry of surface modification and the behavior of photoexcited charge transfer at the interface during PV and PEC processes will be discussed and possible strategies to improve their performance are discussed.
Journal ArticleDOI

High efficiency hybrid PEDOT:PSS/nanostructured silicon Schottky junction solar cells by doping-free rear contact

TL;DR: In this article, a high power conversion efficiency of 13.7% with a device area of 0.8 cm2 has been achieved for organic-nanostructured Si hybrid solar cells by inserting a cesium carbonate (Cs2CO3) layer between Si and the rear electrode aluminium.
References
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Journal Article

Photoelectrochemical cells : Materials for clean energy

Michael Grätzel
- 01 Jan 2001 - 
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI

Porphyrin-Sensitized Solar Cells with Cobalt (II/III)–Based Redox Electrolyte Exceed 12 Percent Efficiency

TL;DR: In this article, a Co(II/III)tris(bipyridyl)-based redox electrolyte was used in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer (designated YD2-o-C8).
Journal Article

Porphyrin-sensitized solar cells with cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency (vol 334, pg 629, 2011)

TL;DR: Mesoscopic solar cells that incorporate a Co(II/III)tris(bipyridyl)–based redox electrolyte in conjunction with a custom synthesized donor-π-bridge-acceptor zinc porphyrin dye as sensitizer are reported, enabling attainment of strikingly high photovoltages approaching 1 volt.
Journal ArticleDOI

For the Bright Future—Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4%

TL;DR: The past success in organic light-emitting diodes provides scientists with confidence that organic photovoltaic devices will be a vital alternate to the inorganic counterpart, and the easiness of the fabrication holds the promise of very low-cost manufacturing process.
Journal ArticleDOI

Light Trapping in Silicon Nanowire Solar Cells

TL;DR: It is demonstrated that ordered arrays of silicon nanowires increase the path length of incident solar radiation by up to a factor of 73, which is above the randomized scattering (Lambertian) limit and is superior to other light-trapping methods.
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