Journal ArticleDOI
Total Synthesis of L-Allose, L-Talose, and Derivatives
Yves Auberson,Pierre Vogel +1 more
TLDR
In this article, the ketones (+)-1 and (−)-1 were derived from furan and 1-cyanovinyl (1S)-camphanate, respectively.Abstract:
(1S, 4R, 5S, 6S)-5-exo, 6-exo-(Isopropylidenedioxy)-7-oxabicyclo[2.2.1]heptan-2-one ((−)-1) was transformed with high stereoselectivity to L-allose. Similarly, enantiomer (+)-1 was transformed into L-talose. The ketones (+)-1 and (−)-1 were derived from furan and 1-cyanovinyl (1S)-camphanate and 1-cyanovinyl (1R)-camphanate, respectively.read more
Citations
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Journal ArticleDOI
Modern Methods of Monosaccharide Synthesis from Non-Carbohydrate Sources.
Journal ArticleDOI
Derivatives of 7-oxabicyclo[2.2.1]heptane in nature and as useful synthetic intermediates
TL;DR: In this article, Diels-alder-reaction and opening metathesis polymerization are used for diastereoselective bis-hydroxylation and total synthesis.
Book ChapterDOI
Using Ring-Opening Reactions of Oxabicyclic Compounds as a Strategy in Organic Synthesis
Pauline Chiu,Mark Lautens +1 more
TL;DR: In this paper, various methods for the preparation of oxabicyclic compounds, with an emphasis on the stereo and enantioselective synthesis of these substances, are discussed.
Journal ArticleDOI
Synthesis of L-Hexoses.
Journal ArticleDOI
Total, Asymmetric-Synthesis of Deoxypolyoxin-C
Yves Auberson,Pierre Vogel +1 more
TL;DR: In this article, the authors presented a method to solve the problem of gender discrimination in the context of the LGSA-ARTICLE-1990-011, which was created on 2005-11-09, modified on 2017-05-12.
References
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Journal ArticleDOI
Double Asymmetric Synthesis and a New Strategy for Stereochemical Control in Organic Synthesis
TL;DR: In this article, it is shown that double asymmetric induction can be analyzed in terms of the single asymmetric reactions of each of the two chiral reactants, and a new strategy based on this rule for the predictable creation of new chiral centers is discussed and the use of this strategy for the synthesis of sugars and macrolides is presented.
Journal ArticleDOI
Tetrahedron report number 195 (R)- and (S)-2,3-0-isopropylideneglyceraldehyde in stereoselective organic synthesis
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