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Transport of penetrants in the macromolecular structure of coals: VIII. Transport mechanism as a function of temperature

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TLDR
Pyridine transport in 600-850-μm coal microparticles, pre-extracted with pyridine and redried, was studied as a function of time and temperature from 35 to 300 ° C as discussed by the authors.
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This article is published in Thermochimica Acta.The article was published on 1987-06-15. It has received 6 citations till now.

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Journal ArticleDOI

Swelling of Coal in Response to CO2 Sequestration for ECBM and Its Effect on Fracture Permeability

TL;DR: In this article, a volumetric strain of 1.48% and a matrix swelling coefficient of 8.98x10{sup-5} MPa{sup -1} were calculated for the high-rank Selar Cornish coal and low-rank Warndt Luisenthal coal.
Journal ArticleDOI

Argonne Coal Structure Rearrangement Caused by Sorption of CO2

TL;DR: In this paper, attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy was used to measure the sorption of CO{sub 2} on seven Argonne premium coals.
Journal ArticleDOI

Temperature Dependence of Solvent Swelling and Diffusion Processes in Coals

TL;DR: In this paper, the rates of solvent swelling of the Argonne Premium Sample coals have been measured in various organic solvents at various temperatures, and the results show that the extents of swelling, when experim...
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Determination of the kinetics of diffusion in coals by solvent swelling techniques

TL;DR: In this article, a simple technique has been developed for measuring the kinetics of solvent diffusion in coals at various temperatures, based on a well-known method for measuring volumetric swelling of coals by solvents.
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Mechanical Properties and Swelling Behavior of Cross-Linked Natural Rubber/Chitosan Blends

TL;DR: In this article, Dicumyl peroxide was selected as a cross-linking agent and the solvent-resistance properties of these vulcanized natural rubber (NR)/chitosan (CS) blends were investigated by the equilibrium swelling method using benzene as solvent.
References
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Journal ArticleDOI

Transport of penetrants in the macromolecular structure of coals. i. anomalous transport in untreated and pyridine-extracted coals

TL;DR: In this paper, the authors investigated the mechanisms of penetrant transport in coal sections and particles and observed anomalous (non-Fickian) and Case-II transport were observed in much the same way as with glassy polymers.
Journal ArticleDOI

Transport of penetrants in the macromolecular structure of coals III. Dynamic swelling of stiff polymer networks that simulate the coal structure

TL;DR: In this paper, the structure of three cross-linked polymers containing naphthalenic rings in their backbone structure was investigated by dynamic swelling and thermal analytic techniques, and it was determined that the pyridine and n-proplyamine transport in microparticles (40 μm) of these polymers was non-Fickian, often approaching case II transport and sometimes even supercase II transport.
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