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Two-step surface functionalization/alignment strategy to improve CO2/N2 separation from mixed matrix membranes based on PEBAX and graphene oxide
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In this article , a simple method to prepare mixed matrix membranes (MMM) based on Pebax with functionalized/oriented graphene oxide (GO) nanosheets is presented to improve CO 2 /N 2 separation.Abstract:
In this study, a simple method to prepare mixed matrix membranes (MMM) based on Pebax with functionalized/oriented graphene oxide (GO) nanosheets is presented to improve CO 2 /N 2 separation. First, the GO nanosheets were surface modified with different amounts of m-phenylenediamine (mPD) to maximize the CO 2 adsorption affinity and minimize GO agglomeration within the matrix. Then, an external electric field was applied to organize/orient the GO nanosheets (modified and unmodified) during membrane preparation. The separation performance results showed that the CO 2 permeability of unmodified and amine-functionalized GO-filled MMM respectively increased by 1.7 and 2.1 times compared to the neat matrix. This improvement is attributed to the high affinity of amino groups for CO 2 uptake. Furthermore, applying a vertical electric field increased the CO 2 permeability compared to a random GO orientation state by 1.3 and 2.8 times for the unmodified and modified GO-filled MMM, respectively. This significant improvement is related to a lower tortuosity in the membrane, improving the passage of gas molecules. Overall, the combination of surface treatment (amino group) and orientation (electric field) on GO nanosheets leads to better CO 2 permselectivity for the membranes studied. read more
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Recent Progress in Ternary Mixed Matrix Membranes for CO2 Separation
Zikang Qin,Yulei Ma,Jing Wei,Hongfang Guo,Bangda Wang,Jing Deng,Chunhai Yi,Na Liu,Shouliang Yi,Wenju Jiang,Lu Yao,Lin Yang,Zhongde Dai +12 more
TL;DR: In this article , the authors introduce the structure and fabrication processes for ternary MMMs, categorizes various nanofillers and the third component, and summarizes and analyzes in detail the CO2 separation performance of newly developed TernaryMMMs based on both rubbery and glassy polymers.
References
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TL;DR: In this paper, a review of the fundamental concepts that have to be considered to prepare various types of MMMs, including considerations for the design novel MMMs that will eventually surpass the Robeson's trade-off upper bound.
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FTIR Spectroscopy for Carbon Family Study
TL;DR: The FTIR vibrational spectroscopy is presented, without claiming to cover entire field, for the characterization of diamond, amorphous carbon, graphite, graphene, carbon nanotubes, fullerene and carbon quantum dots.