Journal ArticleDOI
Ultrafine Mn3O4 Nanowires/Three-Dimensional Graphene/Single-Walled Carbon Nanotube Composites: Superior Electrocatalysts for Oxygen Reduction and Enhanced Mg/Air Batteries.
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TLDR
Combining the ultrafine Mn3O4 nanowires/three-dimensional graphene/single-walled carbon nanotube as an efficient electrocatalyst for the oxygen reduction reaction and an Mg micro-/nanoscale anode in the novel electrolyte, the advanced Mg/air batteries demonstrated a high cell open circuit voltage, a high plateau voltage, and a long discharge time, showing a high energy density.Abstract:
The exploration of highly efficient catalysts for the oxygen reduction reaction to improve sluggish kinetics still remains a great challenge for advanced energy conversion and storage in metal/air batteries. In this work, ultrafine Mn3O4 nanowires/three-dimensional graphene/single-walled carbon nanotube catalysts with an electron transfer number of 3.95 (at 0.60 V vs Ag/AgCl) and kinetic current density of 21.7–28.8 mA cm–2 were developed via a microwave-irradiation-assisted hexadecyl trimethylammonium bromide (CTAB) surfactant procedure to greatly enhance the overall catalytic performance in Mg/air batteries. To match the electrochemical activity of the cathode catalysts, a large-scale Mg anode prepared with micropersimmon-like particles via a mechanical disintegrator and Mg(NO3)2–NaNO2-based electrolyte containing 1.0 wt % trihexyl(tetradecyl)phosphonium chloride ionic liquid were applied. Combining the ultrafine Mn3O4 nanowires/three-dimensional graphene/single-walled carbon nanotube as an efficient el...read more
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Journal ArticleDOI
Spinels: Controlled Preparation, Oxygen Reduction/Evolution Reaction Application, and Beyond
TL;DR: The physicochemical characteristics of spinels such as their compositions, structures, morphologies, defects, and substrates have been rationally regulated through various approaches and can yield spinels with improved ORR/OER catalytic activities, which can further accelerate the speed, prolong the life, and narrow the polarization of fuel cells, metal-air batteries, and water splitting devices.
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Aqueous metal-air batteries: Fundamentals and applications
TL;DR: In this paper, a general description of the features and working principles of aqueous metal-air battery systems are presented, as well as the air cathode structures are introduced and compared.
Journal ArticleDOI
Transition metal oxide-based oxygen reduction reaction electrocatalysts for energy conversion systems with aqueous electrolytes
TL;DR: In this article, the authors provide a comprehensive review of the recent progress in transition metal oxide-type catalysts for the ORR in aqueous media, including simple transition metal oxides, perovskite type catalysts, spinel-type catalyst, and other ternary transition metal Oxides catalysts.
Journal ArticleDOI
Current Progress on Rechargeable Magnesium–Air Battery
TL;DR: A comprehensive and concise survey of the major progress in the history of secondary Mg-air batteries, and detailed illustrations of corresponding reaction mechanisms can be found in this article, which is devoted to open up a new area for manipulating the nanostructures to control the ideal reaction pathway in novel cell configuration and to fully understand the future Mg−air battery with improved energy density and cycling ability.
References
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Journal ArticleDOI
Building better batteries
TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
Journal ArticleDOI
Li-O2 and Li-S batteries with high energy storage.
Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI
Lithium−Air Battery: Promise and Challenges
TL;DR: In this article, the authors summarized the promise and challenges facing development of practical Li−air batteries and the current understanding of its chemistry, and showed that the fundamental battery chemistry during discharge is the electrochemical oxidation of lithium metal at the anode and reduction of oxygen from air at the cathode.
Journal ArticleDOI
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts
Fangyi Cheng,Jun Chen +1 more
TL;DR: The battery electrochemistry and catalytic mechanism of oxygen reduction reactions are discussed on the basis of aqueous and organic electrolytes, and the design and optimization of air-electrode structure are outlined.
Journal ArticleDOI
Metal–Air Batteries with High Energy Density: Li–Air versus Zn–Air
TL;DR: Li-air and Zn-air batteries have been studied extensively in the past decade as mentioned in this paper, with the aim of providing a better understanding of the new electrochemical systems, and metal-air battery with conversion chemistry is a promising candidate.