Journal ArticleDOI
Umsetzungen von säurechloriden mit trimethylsilyldiphenylphosphin : I. Über die einwirkung von triphenylphosphin und trimethylsilyldiphenylphosphin auf die isomeren phthalylchloride
H. Kunzek,Klaus Rühlmann +1 more
TLDR
In this article, the reaction of the two isomeric phthalyl chlorides (I and (IV), respectively, with molar amounts of trimethylsilyldiphenylphosphine (IIa) or triphenyl phosphine(IIb) yields trans-diphthalyl (III) as the main product.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1972-09-01. It has received 9 citations till now. The article focuses on the topics: Phthalide & Triphenylphosphine.read more
Citations
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Journal ArticleDOI
ACYL- AND ALKYLIDENEPHOSPHINES. XXI.1 Acylphosphines and Their Derivatives with Phosphorus Atoms of Coordination Number 3, 2, and 1
TL;DR: In this article, the authors summarized their work on acylphosphines and alkylidene-alkylide-phosphine compounds under ordinary conditions and showed that these compounds exist only thirty years ago.
Journal ArticleDOI
Bildung und Eigenschaften von Acylphosphanen. IX. Reaktion von Phenylbis(trimethylsilyl)phosphan mit Formaldehyd und Dimethylformamid
Gerd Becker,O. Mundt +1 more
TL;DR: In this paper, an addition-elimination reaction yields hexamethyldisiloxane 6 and N,N-dimethylaminomethyliden-phenylphosphane 5.
Journal ArticleDOI
Darstellung und Eigenschaften von Derivaten des 2,3‐Bis(di‐phenylphosphino)maleinsäure‐anhydrids als Beitrag zum Problem der Farbigkeit, Konjugationsbeeinflussung und Komplexbildung dieser Stoffklasse
Dieter Fenske,Hermann J. Becher +1 more
TL;DR: In this article, a 2,3-Bis(diphenylphosphino)maleic anhydride with the aid of diphenyl(trimethylsilyl)phosphine was synthesized.
Journal ArticleDOI
Umsetzungen von säurechloriden mit trimethylsilyldiphenylphosphin
TL;DR: Aromatic acid chlorides react with trimethylsilyldiphenylphosphine (I) to give the acid phosphides (IIa-i) and (V), and the acid chloride phosphide (IV).
Book ChapterDOI
Synthesis and Reactions of Phosphorus-Rich Silylphosphanes
TL;DR: In this paper, the basic knowledge of the chemistry of silylphosphanes was broadened with the goal of permitting a full understanding of the reactions of these reactions with PH-containing lithium phosphides.
References
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Journal ArticleDOI
Structure et réactions du composé d'addition: triphénylphosphine ‐ anhydride maléique
R. F. Hudson,P. A. Chopard +1 more
TL;DR: The structure of the adduct between maleic anhydride and triphenylphosphine has been determined by direct synthesis and spectral analysis as mentioned in this paper, analogous to a phosphine methylene derivative (WITTIG reagent) stabilized by an u-carbonyl group.
Journal ArticleDOI
Photochemische Reaktionen des Benzocyclobuten‐dions‐(1.2)
Heinz A. Staab,Junes Ipaktschi +1 more
TL;DR: In this article, a few Versuche zur Darstellung von Benzocyclopropenen werden mitgeteilt, e.g., the Reaktion mit Athanol zu 3-Athoxy-phthalid (9), die Abfangreaktionen von 12 with Dienophilen and die Carben-Reaktionsen von 13 with Alkenen and Alkinen stutzen diese Annahme.
Journal ArticleDOI
New Reactions of Phosphite Esters: The Conversion of Phthalic Anhydride into Biphthalyl by Trialkyl Phosphites and into Phthalide-3-phosphonates by Dialkyl Phosphites1
Journal ArticleDOI
The reaction of tervalent phosphorus compounds with dichlorodiphenylmethane
KL Freeman,MJ Gallagher +1 more
TL;DR: In this paper, the origin of the products is discussed in terms of attack of phosphorus at halogen and carbon, and the initial step in these reactions does not seem to be the initial stage.