Journal ArticleDOI
Versatile nuclearity in copper complexes with ortho functionalized 1,3-bis(aryl)triazenido ligands
Juan José Nuricumbo-Escobar,Carlos Campos-Alvarado,Fernando Rocha-Alonso,Gustavo Ríos-Moreno,David Morales-Morales,Herbert Höpfl,Miguel Parra-Hake +6 more
TLDR
In this paper, the synthesis, characterization and crystal structures of three new copper complexes derived from 1,3-bis(aryl)triazenido ligands bearing either a methoxy carbonyl, methylthio or a hydroxymethyl group in the ortho position of one of the aromatic rings are reported.About:
This article is published in Inorganica Chimica Acta.The article was published on 2010-04-05. It has received 11 citations till now. The article focuses on the topics: Triazene & Aryl.read more
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Manganese complexes with triazenido ligands encapsulated in NaY zeolite as heterogeneous catalysts
TL;DR: In this paper, two different methods were described for the preparation of manganese complexes with triazenido derivative ligands encapsulated in NaY zeolite, and the catalytic behavior of the heterogeneous catalysts was evaluated for styrene and cyclohexanol oxidation reactions.
Journal ArticleDOI
Halochromism, ionochromism, solvatochromism and density functional study of a synthesized copper(II) complex containing hemilabile amide derivative ligand.
TL;DR: Density functional theory, DFT calculations were performed in order to study the electronic structure of the complex, the relative stabilities of the CuN/CuO isomers, and to understand the nature of the halochromism processes taking place.
Journal ArticleDOI
Synthesis, structures and catalytic activity of 1,3-bis(aryl)triazenide( p -cymene)ruthenium(II) complexes
Erick Correa-Ayala,Aida Valle-Delgado,Gustavo Ríos-Moreno,Daniel Chávez,David Morales-Morales,Simón Hernández-Ortega,Juventino J. García,Marco Flores-Álamo,Valentín Miranda-Soto,Miguel Parra-Hake +9 more
TL;DR: In this paper, the synthesis, characterization, crystal structures and catalytic activity of four new 1,3-bis(aryl)triazenide(p-cymene)ruthenium(II) complexes bearing methoxy carbonyl (5), hydroxymethyl (6), acetylphenyl (7) in the ortho position, and methyl in the para position (8) were reported.
Journal ArticleDOI
Chelation-Assisted Interrupted Copper(I)-Catalyzed Azide–Alkyne–Azide Domino Reactions: Synthesis of Fully Substituted 5-Triazenyl-1,2,3-triazoles
TL;DR: In this paper, the synthesis of 1,4-(disubstituted)-5-triazenyl-1,2,3 -triazoles through a ligand-free domino copper(I)-catalyzed azide-alkyne-azide process of chelating aryl azides bearing N-P═O, P═O and SO3H groups at the ortho position was described.
Journal ArticleDOI
Triazenide complexes of iridium. Evidence for [Ir(η1-N3Ph2)(HN3Ph2)(1,5-cod)], structures of [Ir2(μ-OMe)2(1,5-cod)2], [Ir2(μ-N3Ph2)2(1,5-cod)2], [Ir(η2-N3Ph2)(H)(SiPh3)(1,5-cod)], [Ir(η2-N3Ph2)(H)(SnPh3)(1,5-cod)] and [Ir(η2-N3Ph2)(SC6F5)2(1,5-cod)]
TL;DR: In this article, the reaction of [Ir2(μ-OMe)2(1,5-cod)2] with diphenyltriazene gives a product, formulated as [Ir(η1-N3Ph2)(HN3P2)(1, 5-cod)] on the basis of NMR data.
References
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Book
Inorganic Chemistry: Principles of Structure and Reactivity
TL;DR: In this article, inorganic chemistry principles of structure and reactivity are presented. But, they do not cover how to use these principles in the design of products, and they are not available in any type of product.
Journal ArticleDOI
Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline‐Based Systems
Pierre Braunstein,Frédéric Naud +1 more
TL;DR: The definition and scope of hemilabile ligands are recalled, the main classes of ligands containing one or more oxazoline moieties are presented, with an emphasis on hybrid ligands, and why the combination of these two facets of ligand design appears particularly promising are explained.
Journal ArticleDOI
Triazenes: a versatile tool in organic synthesis.
TL;DR: This review highlights some of the recent advances and diversity possible with triazenes, a class of compounds which are stable and adaptable to numerous synthetic transformations.
Journal ArticleDOI
The crystal structure of diazoaminobenzene copper(I)
I. D. Brown,Jack D. Dunitz +1 more
TL;DR: BERGHUIS, J., HAANAPPEL, IJ.M., POTTERS, M., LooPSTRA, B. REIHLE:N, I-I.