Journal ArticleDOI
Versatile PdTe/C catalyst for liquid-phase oxidations of 1,3-butadiene
N. I. Kuznetsova,V. N. Zudin,L. I. Kuznetsova,Vladimir I. Zaikovskii,H. Kajitani,M. Utsunomiya,Kazunari Takahashi +6 more
TLDR
A commercial Pd catalyst based on Sibunit carbon support was treated with H6TeO6 in a reducing media to obtain a Te coating on the surface of Pd particles as discussed by the authors.Abstract:
A commercial Pd catalyst based on Sibunit carbon support was treated with H6TeO6 in a reducing media to obtain a Te coating on the surface of Pd particles. The PdTe/C catalyst prepared in this way showed the ability to control the radical chain oxidation of 1,3-butadiene by promoting the selective formation of 2-butene-1,4-diol, 4-hydroxybut-2-enal and furan in DMA (total selectivity of 61% and yield of 7%). At the same time, the catalyst induced oxidation of 1,3-butadiene by a non-radical heterolytic mechanism involving the formation of two groups of primary products: (1) сrotonaldehyde and methyl vinyl ketone and (2) the products of oxygenation at the 1,4-positions. The compounds of the second group including 1,4-dimethoxy-2-butene and maleic acid dimethyl ester were formed on PdTe centers in MeOH. Increasing the Te concentration in the PdTe/C catalyst forced the conversion of 1,3-butadiene toward 1,4-oxygenation and simultaneously decreased the intensity of secondary oxidation, resulting in the selective formation of derivatives of the 1,4-oxygenation—1,4-dimethoxy-2-butene and allenic alcohol methyl ether (total selectivity of 84% and yield of 48%).read more
Citations
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Journal ArticleDOI
Direct transformation of terminal alkenes with H2O into primary alcohols over metal oxide-supported Pd catalysts
Zhenzhong Zhang,Tetsuya Mamba,Eiji Yamamoto,Haruno Murayama,Tamao Ishida,Tetsuo Honma,Tadahiro Fujitani,Makoto Tokunaga +7 more
TL;DR: In this paper, a novel access for the transformation of terminal alkenes with H2O into the corresponding primary alcohols over metal oxide-supported Pd catalysts, employing O2 as the sole oxidant.
Journal ArticleDOI
Allylic C–H acetoxylation of terminal alkenes over TiO2 supported palladium nanoparticles using molecular oxygen as the oxidant
TL;DR: In this paper, a method for synthesizing linear allylic acetates from terminal alkenes over TiO 2 supported Pd nanoparticles (NPs) was developed, in which O 2 serves as the sole oxidant.
Book ChapterDOI
N,N‐Dimethylformamide and N,N‐Dimethylacetamide as Carbon, Hydrogen, Nitrogen, and/or Oxygen Sources
Jean Le Bras,Jacques Muzart +1 more
Journal ArticleDOI
Synthesis and Characterization of PtTe 2 Multi-Crystallite Nanoparticles using Organotellurium Nanocomposites
Javier Fernández-Lodeiro,Javier Fernández-Lodeiro,Benito Rodríguez-González,Fernando Novio,Adrián Fernández-Lodeiro,Daniel Ruiz-Molina,José Luis Capelo,Alcindo A. dos Santos,Carlos Lodeiro +8 more
TL;DR: The synthesis of new PtTe2 multi-crystallite nanoparticles (NPs) in different sizes through an annealing process using new nanostructured Pt-Te organometallic NPs as a single source precursor could be successfully size controlled in the nanoscale range.
References
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Journal ArticleDOI
Stereo- and regioselective palladium-catalyzed 1,4-diacetoxylation of 1,3-dienes
TL;DR: L'oxydation catalysee par Pd de dienes-1,3 dans l'acide acetique en utilisant MnO 2 comme oxydant et des quantites catalytiques de benzoquinone-1.4-alcenes-2.
Journal ArticleDOI
The direct epoxidation of higher olefins using molecular oxygen
TL;DR: In this article, a bifunctional catalysts that combine new catalyst components that generate such oxidants as H2O2 in situ with the functional component that activates H 2O2 for olefin epoxidation is presented.
Journal ArticleDOI
The Effect of Pretreatment on Pd/C Catalysts: I. Adsorption and Absorption Properties
TL;DR: In this article, a high surface area carbon black was pre-treated at 1223 K under H 2 or Ar to remove sulfur contaminants and oxygen-containing functional groups on the surface.
Journal ArticleDOI
Nano-size particles of palladium intermetallic compounds as catalysts for oxidative acetoxylation
TL;DR: In this article, fine particles of palladium containing intermetallic compounds (IMCs) were prepared on the surface of silica gel and their catalytic properties for the oxidative acetoxylation of toluene and 1,3-butadiene (BD) were investigated.
Journal ArticleDOI
Aerobic oxidation of diverse primary alcohols to methyl esters with a readily accessible heterogeneous Pd/Bi/Te catalyst.
Adam B. Powell,Shannon S. Stahl +1 more
TL;DR: Efficient aerobic oxidative methyl esterification of primary alcohols has been achieved with a heterogeneous catalyst consisting of 1 mol % Pd/charcoal (5 wt %) in combination with bismuth(III) nitrate and tellurium metal.