scispace - formally typeset
Journal ArticleDOI

Visible-light photoredox-promoted desilylative allylation of α-silylamines: An efficient route to synthesis of homoallylic amines

Reads0
Chats0
TLDR
In this article, a facile and efficient synthesis of homoallylic amines by visible-light photoredox-promoted desilylative allylation of α-silylamines with allylic sulfones is described.
About
This article is published in Tetrahedron Letters.The article was published on 2021-09-28. It has received 25 citations till now. The article focuses on the topics: Allylic rearrangement.

read more

Citations
More filters
Journal ArticleDOI

Performance, combustion and emission characteristics investigations on a diesel engine fueled with diesel/ ethanol /n-butanol blends

TL;DR: In this paper , a three-dimensional computational fluid dynamics (CFD) model of a diesel engine cylinder was developed by AVL-Fire software, and a chemical reaction mechanism containing 377 reactions and 81 species was established by the CHEMKIN program.
Journal ArticleDOI

Investigation on the combustion and emission characteristics of diesel engine fueled with diesel/methanol/n-butanol blends

TL;DR: In this paper , the effects of different fuel blending ratios on the spray, combustion, and emission characteristics of diesel engine in terms of cylinder pressure, cylinder temperature, heat release rate, brake specific fuel consumption, brake power, brake thermal efficiency, NOx emission, soot emission, CO emission, and HC emission.
Journal ArticleDOI

The effects of Mn-based catalysts on the selective catalytic reduction of NOx with NH3 at low temperature: A review

TL;DR: In this article , the progress of research on Mn-based catalysts for selective catalytic reduction of NOx at low temperatures is reviewed, and the prospects and future directions for the development of Mnbased low-temperature selective catalyst reduction catalysts are presented.
Journal ArticleDOI

The development of diesel oxidation catalysts and the effect of sulfur dioxide on catalysts of metal-based diesel oxidation catalysts: A review

TL;DR: In this paper , the status, preparation methods, the influence and measures of sulfur dioxide (SO2) on catalysts, and the methods of developing anti-SO2 catalysts in the future of diesel oxidation catalyst were discussed.
Journal ArticleDOI

Effect of assisted hydrogen on combustion and emission characteristics of a diesel engine fueled with biodiesel

TL;DR: In this article , the effects of hydrogen assisted biodiesel with different fatty acid methyl esters (FAMEs) proportion on cylinder pressure, cylinder temperature, indicated thermal efficiency (ITE), NOx emission, HC emission and CO emission of a marine medium speed diesel engine are studied.
References
More filters
Journal ArticleDOI

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

TL;DR: The conversion of these bench stable, benign catalysts to redox-active species upon irradiation with simple household lightbulbs represents a remarkably chemoselective trigger to induce unique and valuable catalytic processes.
Journal ArticleDOI

Synthetic applications of eosin Y in photoredox catalysis

TL;DR: The key photophysical properties of the dye are summarized and the recent synthetic applications in photoredox catalysis are summarized.
Journal ArticleDOI

Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

TL;DR: A photoredox-catalyzed C–H arylation reaction for the construction of benzylic amines is discovered, an important structural motif within pharmaceutical compounds that is not readily accessed via simple substrates.
Journal ArticleDOI

Amine Functionalization via Oxidative Photoredox Catalysis: Methodology Development and Complex Molecule Synthesis.

TL;DR: The presence of tertiary amines in numerous alkaloids, pharmaceuticals, and agrochemicals lends credence to the potential utility of this chemistry in natural product synthesis, and herein it is discussed how these transformations might be controlled for synthetic purposes.
Journal ArticleDOI

Carboxylic acids as a traceless activation group for conjugate additions: a three-step synthesis of (±)-pregabalin.

TL;DR: Photon-induced oxidation of a broad series of carboxylic acids, including hydrocarbon-substituted, α-oxy, and α-amino acids, provides a versatile CO2-extrusion platform to generate Michael donors without the requirement for organometallic activation or propagation.
Related Papers (5)