Journal ArticleDOI
Zinc and cadmium
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TLDR
Caracterisation structurale d'une serie de complexes du zinc and du nickel avec des coordinats diversifies: pseudohalogenures, donneurs azotes ou oxygenes, amines, bases de Schiff as discussed by the authors.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1985-03-01. It has received 63 citations till now. The article focuses on the topics: Zinc & Cadmium.read more
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Differential metal-specific tolerance and accumulation patterns among Thlaspi caerulescens populations originating from different soil types.
Ana G. L. Assunção,Wilma M. Bookum,H. J. M. Nelissen,Riet Vooijs,Henk Schat,Wilfried H. O. Ernst +5 more
TL;DR: In this paper, Thlaspi caerulescens populations from contrasting soil types (serpentine, calamine and nonmetalliferous) were characterized with regard to tolerance, uptake and translocation of zinc (Zn), cadmium (Cd) and nickel (Ni) in hydroponic culture.
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Ni-induced oxidative stress in roots of the Ni hyperaccumulator, Alyssum bertolonii.
TL;DR: Compared with N. tabacum, oxidative damage may be minimised in A. bertolonii roots by high endogenous activities of catalase and, to a lesser extent, superoxide dismutase andCatalase, and enhanced mechanisms for tolerating active oxygen species may also be present.
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Acidification of lead/zinc mine tailings and its effect on heavy metal mobility
TL;DR: The diethylenetetramine pentaacetic acid (DTPA)-extractable Pb, Zn, Cu, and Cd concentrations of acidified tailings surface were significantly higher than those of nonacidify tailings, which revealed that acidification enhanced the mobility of heavy metals in the tailings.
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Metal Sulfide Complexes and Clusters
David Rickard,George W. Luther +1 more
TL;DR: In this article, the authors show that metal sulfide complexes and clusters enhance the solubility of metal sulfides in natural aqueous systems, explaining the transport of metals in sulfidic solutions and driving the biology and ecology of some systems.
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Evidence for aqueous clusters as intermediates during zinc sulfide formation
TL;DR: In this paper, the authors demonstrate a plausible stepwise process for the formation of minerals from low temperature aqueous solutions using zinc sulfide as an example and demonstrate that sulfide clusters form at concentrations of 20 μM (or less) of metal and bisulfide.
References
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Sapphyrins: novel aromatic pentapyrrolic macrocycles
Victor J. Bauer,Derrick L. J. Clive,David Dolphin,John B. Paine,Francis Laurie. Harris,Michael M. King,John Loder,Shen Wei Chien Wang,Robert B. Woodward +8 more
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Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins
K. A. Macor,T. G. Spiro +1 more
TL;DR: In this article, the resonance Raman spectrum of the NiPP film indicates that one of the two vinyl groups is saturated on most of the porphyrin units, which is consistent with a mechanism involving electroinitiated cationic vinyl polymerization.
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Reversible oxidation and rereduction of entire thin films of transition-metal phthalocyanines
J.M. Green,L.R. Faulkner +1 more
TL;DR: In this paper, it was shown that ZnPc films oxidized to the extent of 1.21 electrons per Zn Pc molecule and CoPc required 1.92 electrons per molecule.
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Chemistry of the imidazolate-bridged bimetallic center in the copper-zinc superoxide dismutase and its model compounds
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Molecular structures, electronic spectra, and ESR spectra of bis(4,4',5,5'-tetramethyl-2,2'-biimidazole)copper(II) dinitrate and bis(4,4',5,5'-tetramethyl-2,2'-biimidazole)zinc(II)0.90copper(II)0.10 dinitrate
Ernest Bernarducci,Parimal K. Bharadwaj,Roger A. Lalancette,Karsten Krogh-Jespersen,Joseph A. Potenza,Harvey J. Schugar +5 more
TL;DR: Les spectres electronique et RPE ont ete realises sur des complexes a coordinats parents du bi-imidazole, and la structure electronique calculee par les methodes INDO/s et HOMO.