A
Alexander J. Blake
Researcher at University of Nottingham
Publications - 1136
Citations - 37892
Alexander J. Blake is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 89, co-authored 1133 publications receiving 35746 citations. Previous affiliations of Alexander J. Blake include University of Illinois at Chicago & University of Wisconsin-Madison.
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Synthesis of cationic half-sandwich rhodium(I) complexes of 1,4,7-trithiacyclononane ([9]aneS3). The single-crystal structures of [Rh([9]aneS3)(C2H4)2]PF6, [Rh([9]aneS3)(C8H12)]BF4 and [Rh([9]aneS3)(C4H6)]PF6·0.25OEt2
TL;DR: In this paper, a quasi-square pyramidal complex cation was shown to have a high electrophilic character with a trigonal-bipyramidal geometry, with one equatorial and one axial ethene ligand.
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Heterocyclic compounds with bridgehead nitrogen atoms. Part 11. Formation of azocino[2,1,8-cd]pyrrolizines in the reactions of indolizines with dimethyl acetylenedicarboxylate
TL;DR: In this paper, it was shown that 1 : 1 and 1 : 2-adducts obtained from 6- and 7-methyl-2-phenylindolizines are also derivatives of the annulene ring system.
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Hydrido platinum metal macrocyclic complexes: the synthesis and single-crystal X-ray structure of cis-[IrCl(H)L1]PF6{L1=7-methyl-3,7,11,17-tetrazabicyclo[11.3.1]heptadeca-1(17),13,15-triene}
TL;DR: In this paper, the hydridoiridium(III) complex [IrCl(H)L1]PF6.3 was shown to have a single-crystal X-ray structure with octahedral IrIII bound to the folded pyridine-2,6-diyl macrocycle L1.
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catena-Poly[[trans-dichlorocopper(II)]-μ-1,4,7,10,13,16- hexathiacyclooctadecane-S1:S10]
TL;DR: In the title complex of [CuCl2(C12H24S6)]n, the CuCl2 unit and ligand lie on and about inversion centres, respectively, in the coordination geometry at CuII, a tetragonally elongated octahedron with the equatorial positions occupied by two chlorides, Cu-Cl 2.2786 (12)
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Isolation and structural characterisation of products from the reaction of [Os4(µ-H)4(CO)10(MeCN)2] with cyclohexa-1,3-diene
Brian F. G. Johnson,Caroline M. Martin,Alexander J. Blake,David W. Reed,Dario Braga,Fabrizia Grepioni +5 more
TL;DR: The activated tetraosmium hydrido cluster, [Os4(µ-H)4(CO)10(MeCN)2]1, reacts with cyclohexa-1,3-diene producing a range of tetraosa-mium derivatives including the known clusters [Oss4µH)3(CO]11( µ-η1 : η2-C6H9)]2, as mentioned in this paper.