Alexander J. Blake

TL;DR: In this article, the crystal and molecular structure of trimethylindium was determined, and it was shown that it adopts a tetrameric form in the crystal at 273 K. The Raman spectrum of the crystalline solid showed bands close to those reported for the liquid, but there are splittings for some of the e′ modes that are consistent with the loss of three-fold symmetry in each molecular unit; no clear evidence for any additional bands that might be ascribed to the intermolecular links is found.

TL;DR: An unprecedented ligand-based binding domain for D2 within a porous metal–organic framework (MOF) material as confirmed by neutron powder diffraction studies of D2-loaded MFM-132a shows exceptional volumetric hydrogen adsorption and the highest density of adsorbed H2 within its pores among all the porous materials reported to date.

TL;DR: Three-fold deprotonation of 1 with n-butyllithium afforded the corresponding tri-lithium tris(N-arylamido-dimethylsilyl)methane etherate [HC{SiMe(2)N(Li)Ar}(3)(OEt(2))] (2) in 92% yield.

TL;DR: In this paper, the Schiff base 2]-(E)-(quinolin-3-ylimino)methylphenol (H-QMP) was crystallized in Pc space group and complexed with Ni(II) and Co(II), and calculated activation energies and order of pyrolysis were calculated using Horowitz-Metzger method.