A
Alexander J. Blake
Researcher at University of Nottingham
Publications - 1136
Citations - 37892
Alexander J. Blake is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 89, co-authored 1133 publications receiving 35746 citations. Previous affiliations of Alexander J. Blake include University of Illinois at Chicago & University of Wisconsin-Madison.
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Agostic Pd ⋯ H+⋯ NHR2 and apical Pd ⋯ NHR2 interactions: the synthesis and structures of [PdIICl2(H[9]aneN3)]+, the PdII–PdII dimer [(H[9]aneN3)Cl2Pd–PdCl2(H[9]aneN3)]2+, and [Pd(Me3[9]aneN3)(NCMe)2]2+
TL;DR: Long-range agnostic Pd ⋯ H+⋯ NHR2 interactions are observed in the crystal structure of the protonated form of cis-[PdIICl2([9]aneN3)], while a direct apical Pd⋽ NHR 2 interaction is observed in a purple complex [Pd(Me3[9]ANEN3)(NCMe)2](PF6)2].
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Synthesis and Characterization of Fulvene Derivatives of the Ruthenium Carbido Cluster [Ru6C(CO)17]
Alexander J. Blake,Paul J. Dyson,Brian F. G. Johnson,Simon Parsons,David Reed,Douglas S. Shephard +5 more
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exo-Binding of Na+ between two fusedcalix[4]arenes and endo binding of Na+ within thecalix[4]arene cones in the disodium salt of 1,3-dimethyl etherp-tert-butylcalix[4]arene
TL;DR: The reaction of 1,3-dimethyl ether with 1,tert-butylcalix (4) with sodium======¯¯¯¯hydride in tetrahydrofuran affords the dimeric metallocalixarene species, which possesses a novel structure in which ions are coordinated in two very different environments.
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Platinum metal complexes of mixed thia/oxa ionophores. The synthesis and single-crystal X-ray structures of [Pd([15]aneS2O3)2][PF6]2 and [RuCl(PPh3)([15]aneS2O3)2]PF6·H2O ([15]aneS2O3= 1,4,7-trioxa-10,13-dithiacyclopentadecane)
TL;DR: In this article, the synthesis and characterisation of a series of mixed thia/oxa donor macrocyclic complexes was described, including [MCl2(M = Pd or Pt) with one molar equivalent of [15]aneS2O3] and [RuCl(PPh3)3] with two molar equivalents of this article.
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S-Cylindrophane: von pinzettenähnlich strukturierten Metallkomplexen zu Sandwichkomplexen
TL;DR: In this paper, ein statistischen Studie der η6-Koordination in Festkorpern konnen Aren-Metall-Wechselwirkungen with Abstanden von 2.5 bis 3.5 A tatsachlich als Bindungen angesehen werden.