A
Alexander J. Blake
Researcher at University of Nottingham
Publications - 1136
Citations - 37892
Alexander J. Blake is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 89, co-authored 1133 publications receiving 35746 citations. Previous affiliations of Alexander J. Blake include University of Illinois at Chicago & University of Wisconsin-Madison.
Papers
More filters
Journal ArticleDOI
Ruthenium complexes of thioether/oxa ionophores: the synthesis and single-crystal X-ray structures of [RuCl2(PPh3)2([15]aneS2O3)], [RuCl(PPh3)([18]aneS2O4)2]PF6, [RuCl(p-MeC6H4i-Pr)([15]-aneS2O3)]PF6, [RuCl(C6H6)([18]aneS2O4)]X (X = PF6 or BPh4) and [Ru(C5H5)(PPh3)([18]aneS2O4)PF6, ([15]aneS2O3 = 1,4,7-trioxa-10,13-dithiacyclopentadecane; [18]aneS2O4 = 1,4,7,10-tetraoxa-13,16-dithiacyclooctadecane)
Michael N. Bell,Alexander J. Blake,Robert O. Gould,Simon Parsons,Christian Radek,Martin Schröder +5 more
TL;DR: In this paper, RuCl2(PPh3)3 with one molar equivalent of [15]aneS2O3 was shown to yield the complex [RuCl2[15]-aneS 2O3]·1/2Et2O showing RuII in an octahedral Cl2S2P2 environment: 600-01(1), 2.4447(15); 600-02(2),2.4154(15).
Journal ArticleDOI
Crystal structure of 2,4-dimethyl-benzo-1,5-diazepinium hexafluorophosphate, C11H13N2PF6
Journal ArticleDOI
Reaction of imidazoline-2-selone derivatives with mesityltellurenyl iodide: a unique example of a 3c-4e Se→Te←Se three-body system embedding a tellurenyl cation
M. Carla Aragoni,Massimiliano Arca,Alexander J. Blake,Enzo Cadoni,Lucian Copolovici,Francesco Isaia,Vito Lippolis,Sergio Murgia,Alexandra Pop,Cristian Silvestru,Jeremiah P. Tidey,Richard A. Varga +11 more
TL;DR: In this paper, a 3c-4e Se→Te←Se three-body system was characterized by X-ray diffraction analysis for 1,1′-bis(3-methyl-4-imidazolin-2-selone)methane with mesityltellurenyl iodide (MesTeI) [Mes = 2,4,6-Me3C6H2] yielded the neutral [L1·2MesTEI]·2CH2Cl2] and ionic [L2·
Journal ArticleDOI
Synthetic Studies on the Cladiellins (Eunicellins): Unexpected Selenoxide Displacement with Concomitant Alcohol Oxidation During Attempted Selenoxide Elimination
TL;DR: In this paper, an unusual fused tricyclic ketone was obtained as a crystalline solid in high yield and its structure was fully elucidated by X-ray crystallography.
Journal ArticleDOI
Bis(triphenylphosphine)iminium Tetrachlorooxomolybdenum(V) at 150 K
TL;DR: In the title compound [C 36 H 30 NP 2 ] +.[MoOCl 4 ] −, the anions reside in hydrophobic channels formed by the cations and, unlike other salts of this anion, the compound is stable with respect to atmospheric hydrolysis as discussed by the authors.