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Alexander J. Blake

Researcher at University of Nottingham

Publications -  1136
Citations -  37892

Alexander J. Blake is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 89, co-authored 1133 publications receiving 35746 citations. Previous affiliations of Alexander J. Blake include University of Illinois at Chicago & University of Wisconsin-Madison.

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From molecular ribbons to a molecular fabric

TL;DR: Ion-pair reinforced, hydrogen-bonded molecular ribbons are knitted together through ammonium carboxylate salt bridges into undulating sheets wherein each component participates in three ion-pairing interactions and up to twelve hydrogen bonds.
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Early–late, mixed-metal compounds supported by amidophosphine ligands

TL;DR: In this article, a series of discrete early-late mixed-metal complexes supported by the unique amidophosphine ligand m-(But2CH)N(C6H4)PPh2L1 is described.
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Rapid synthesis of the A-E fragment of ciguatoxin CTX3C.

TL;DR: The A-E fragment of the marine natural product CTX3C has been prepared in an efficient manner by using a strategy in which two-directional and iterative ring-closing metathesis (RCM) reactions were employed for ring construction.
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Mercury thioether chemistry: the synthesis and structure of [Hg([9]aneS3)2(PF6)2([9]aneS3=1,4,7-trithiacyclononane)

TL;DR: In this paper, the reaction of HgSO4 with 2 molar equivalents of [9]ANES3 in refluxing H2O-MeOH (1:1 v/v) for 1 h affords a colourless solution from which the complex [Hg([9]aneS3)2](PF6)2 can be isolated by addition of NH4PF6.
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Selective reduction and homologation of carbon monoxide by organometallic iron complexes.

TL;DR: The results indicate that, with the appropriate choice of supporting ligands, it is possible to cleave and homologate carbon monoxide under mild conditions using an abundant and environmentally benign low-coordinate, first row transition metal.