A
Alexander J. Blake
Researcher at University of Nottingham
Publications - 1136
Citations - 37892
Alexander J. Blake is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 89, co-authored 1133 publications receiving 35746 citations. Previous affiliations of Alexander J. Blake include University of Illinois at Chicago & University of Wisconsin-Madison.
Papers
More filters
Journal ArticleDOI
Gas-phase pyrolysis of 1-(2-azidophenyl)imidazole
TL;DR: In this paper, the X-ray crystal structure and NMR properties of the imidazole ring were discussed in detail, and the triplet nitrene intermediate was inserted into the CH bond.
Journal ArticleDOI
Short Synthesis of Chiral 4-Substituted (S)-Imidazolinium Salts Bearing Sulfonates and Their Use in γ-Selective Reactions of Allylic Halides with Grignard Reagents
TL;DR: In this paper, a one-pot reaction of Boc-protected amino alcohols and 2-sulfobenzoic anhydride followed by the addition of a wide variety of primary amines has allowed rapid access to diverse libraries of amidosulfonates 1,2-C6H4(SO3-) (COCHR1CH2NH2+R2) (R1 = Bn, iPr, Ph; R2 = aryl, CHMePh, 1-adamantyl).
Journal ArticleDOI
Palladium(ii)- und Platin(II)-Komplexe mit 1,4,7,10,13,16-Hexathiacyclooctadecan
TL;DR: In this paper, a cristallise dans le systeme monoclinique, groupe d'espace P2 1 /c and sa structure est affinee jusqu'a R=0,0541.
Journal ArticleDOI
Structural influence of cis and trans coordination modes of multi-modal ligands upon coordination polymer dimensionality
TL;DR: In this paper, a ligand donor arrangement leads to structural discrimination between one-and two-dimensions in two coordination frameworks, {[AgNO3]2L}∞, formed between AgNO3 and hexadentate multi-modal ligands.
Journal ArticleDOI
Pinwheel motifs: formation of unusual homo- and hetero-nuclear aggregates via bridging thiolates
Angelo J. Amoroso,Simon S. M. Chung,Douglas J. E. Spencer,Jonathan P. Danks,Mark W. Glenny,Alexander J. Blake,Paul A. Cooke,Claire Wilson,Martin Schröder +8 more
TL;DR: The homohexanuclear complexes [Ni2{Ni(L1)}4]-BF4)4·MeCN, 1, [Pd2{Pd(L2)]4] as discussed by the authors, 2, and the heteropentanuclear aggregate [Cu2{ Ni(L3)}3]-PF6)2, 3] adopt a "pinwheel" type structural motif via thiolate bridging between square-planar Ni(II) or Pd(II), respectively.