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Alexander J. Blake

Researcher at University of Nottingham

Publications -  1136
Citations -  37892

Alexander J. Blake is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 89, co-authored 1133 publications receiving 35746 citations. Previous affiliations of Alexander J. Blake include University of Illinois at Chicago & University of Wisconsin-Madison.

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Selective extraction and transport of the [PtCl6]2- anion through outer-sphere coordination chemistry.

TL;DR: A series of tripodal receptors designed to recognise the outer coordination sphere of the hexachlorometallate anion [PtCl(6)](2-), and thus show selectivity for ion-pair formation over chloride binding, has been synthesised and characterised.
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High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons.

TL;DR: The mononuclear Pd(ii) complex converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.
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An acid labile arginine derivative for peptide synthesis: NG-2,2,5,7,8-pentamethylchroman-6-sulphonyl-L-arginine

TL;DR: A labile protecting group for the guanidine side chain function of arginine has been developed and cleaved rapidly in TFA or 50% TFA in dichloromethane at room temperature.
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Probing the solvent dependent photophysics of fac-[Re(CO)3(dppz-X2)Cl] (dppz-X2 = 11,12-X2-dipyrido[3,2-a:2',3'-c]phenazine); X = CH3, H, F, Cl, CF3).

TL;DR: In this paper, the results of electrochemical measurements, density-functional theory calculations, emission and time-resolved IR (TRIR) spectroscopic studies for fac-[ReCl(CO)3(dppz-X2)], (Dppz = dipyrido[3,2-a:2′,3′-c]phenazine; X = CH3, H, F, Cl, CF3) are reported.