Haitao Zhao

TL;DR: The ruthenium-catalyzed azide-alkyne cycloaddition (RuAAC) appears to proceed via oxidative coupling of the azide and alkyne reactants to give a six-membered rUThenacycle intermediate, in which the first new carbon-nitrogen bond is formed between the more electronegative carbon of the alkynes and the terminal, electrophilic nitrogen of the Azide.

TL;DR: Two algorithms are proposed: a centralized deployment algorithm and a distributed motion control algorithm that enables each UAV to autonomously control its motion, find the UEs and converge to on-demand coverage and the connectivity of the UAV network is maintained.

TL;DR: Simulation results demonstrate that the system performance obtained by the proposed scheme can outperform the benchmark schemes, and the optimal parameter selections are concluded in the experimental discussion.

TL;DR: The detailed reaction mechanism for the reduction of CO2 to CO catalyzed by (NHC)Cu(boryl) complexes was studied with the aid of DFT by calculating the relevant intermediates and transition state structures.

TL;DR: The detailed mechanism for the diboration of aldehydes catalyzed by (NHC)Cu(boryl) complexes was studied with the aid of DFT by calculating the relevant intermediates and transition states to show the "electron-richness" of the Cu- boryl bond gives rise to a small insertion barrier and determines the direction of insertion.